Pt(PPh3)2(C2Ph2)


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas1039. ± 28.kJ/molReviewMartinho SimõesThe enthalpy of formation relies on 194. ± 12. kJ/mol for the enthalpy of formation of cis-Pt(PPh3)2(Cl)2(cr).

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid754. ± 20.kJ/molReviewMartinho SimõesThe enthalpy of formation relies on 194. ± 12. kJ/mol for the enthalpy of formation of cis-Pt(PPh3)2(Cl)2(cr).

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δsub285. ± 20.kJ/molRSCAl Takhin, Skinner, et al., 1984 

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C50H40P2Pt (cr) + Hydrogen chloride (g) = C51H40ClP2Pt (cr)

By formula: C50H40P2Pt (cr) + HCl (g) = C51H40ClP2Pt (cr)

Quantity Value Units Method Reference Comment
Δr-90. ± 6.kJ/molRSCEvans, Mortimer, et al., 1975 

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Al Takhin, Skinner, et al., 1984
Al Takhin, G.; Skinner, H.A.; Zaki, A.A., J. Chem. Soc., Dalton Trans., 1984, 371.. [all data]

Evans, Mortimer, et al., 1975
Evans, A.; Mortimer, C.T.; Puddephatt, R.J., J. Organometal. Chem., 1975, 96, C58. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References