Hf(Cp*)(OC6F5)(Me)2


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C13H24Hf (solution) + Phenol, pentafluoro- (solution) = C18H21F5HfO (solution) + Methane (g)

By formula: C13H24Hf (solution) + C6HF5O (solution) = C18H21F5HfO (solution) + CH4 (g)

Quantity Value Units Method Reference Comment
Δr-42.59 ± 0.31kcal/molRSCSchock and Marks, 1988solvent: Toluene

C18H21F5HfO (solution) + Phenol, pentafluoro- (solution) = C23H18F10HfO2 (solution) + Methane (g)

By formula: C18H21F5HfO (solution) + C6HF5O (solution) = C23H18F10HfO2 (solution) + CH4 (g)

Quantity Value Units Method Reference Comment
Δr-41.11 ± 0.41kcal/molRSCSchock and Marks, 1988solvent: Toluene

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Schock and Marks, 1988
Schock, L.E.; Marks, T.J., J. Am. Chem. Soc., 1988, 110, 7701. [all data]


Notes

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