Ti(Cp)2(Cl)(Me)


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas-125. ± 13.kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -383.6 ± 7.7 kJ/mol for the enthalpy of formation of Ti(Cp)2(Cl)2(cr)

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C11H13ClTi (cr) + (Hydrogen chloride • 4.40Water) (solution) = Titanocene dichloride (cr) + Methane (g)

By formula: C11H13ClTi (cr) + (HCl • 4.40H2O) (solution) = C10H10Cl2Ti (cr) + CH4 (g)

Quantity Value Units Method Reference Comment
Δr-68.9 ± 3.1kJ/molRSCCalhorda, Dias, et al., 1987 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Calhorda, Dias, et al., 1987
Calhorda, M.J.; Dias, A.R.; Minas da Piedade M.E.; Salema, M.S.; Martinho Simões J.A., Organometallics, 1987, 6, 734. [all data]


Notes

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