Ti(OPr)4


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas-355.7 ± 2.2kcal/molReviewMartinho SimõesThe enthalpy of formation relies on -349.24 ± 0.74 kcal/mol for the enthalpy of formation of Ti(OEt)4(l)

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfliquid-373.73 ± 0.88kcal/molReviewMartinho SimõesThe enthalpy of formation relies on -349.24 ± 0.74 kcal/mol for the enthalpy of formation of Ti(OEt)4(l)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δvap18.0 ± 2.0kcal/molRSCBradley and Hillyer, 1966Please also see Pedley and Rylance, 1977.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Bradley and Hillyer, 1966
Bradley, D.C.; Hillyer, M.J., Thermochemistry of metal alkoxides. Part 2.?Heats of formation of some titanium alkoxides, Trans. Faraday Soc., 1966, 62, 2374, https://doi.org/10.1039/tf9666202374 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]


Notes

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