Mg(Br)(Bz)


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

Benzene, (bromomethyl)- (l) + magnesium (cr) = C7H7BrMg (solution)

By formula: C7H7Br (l) + Mg (cr) = C7H7BrMg (solution)

Quantity Value Units Method Reference Comment
Δr-65.9 ± 1.1kcal/molRSCHolm, 1981solvent: Diethyl ether; Due to the possibility of side reactions, the enthalpy of reaction was not considered to be sufficiently reliable for deriving the enthalpy of formation of the Grignard reagent Holm, 1981

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Holm, 1981
Holm, T., J. Chem. Soc., Perkin Trans. II, 1981, 464.. [all data]


Notes

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