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LiOEt


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C2H5LiO (cr) + 0.5(Sulfuric Acid bullet 1100Water) (solution) = 0.5Li2O4S (solution) + Ethanol (solution)

By formula: C2H5LiO (cr) + 0.5(H2O4S bullet 1100H2O) (solution) = 0.5Li2O4S (solution) + C2H6O (solution)

Quantity Value Units Method Reference Comment
Deltar-113.6 ± 1.3kJ/molRSCBlanchard, Joly, et al., 1974solvent: Sulphuric acid aqueous solution; The reaction enthalpy relies on -10.6 kJ/mol for the enthalpy of solution of EtOH(l) and on -17.5±0.3 for the enthalpy of solution of Li2SO4(cr) Blanchard, Joly, et al., 1974.

C2H5LiO (cr) + (Hydrogen chloride bullet 552Water) (solution) = Ethanol (l) + lithium chloride (cr)

By formula: C2H5LiO (cr) + (HCl bullet 552H2O) (solution) = C2H6O (l) + ClLi (cr)

Quantity Value Units Method Reference Comment
Deltar-42.4 ± 3.9kJ/molRSCLeal and Martinho Simões, 1993 

C2H5LiO (cr) + Water (l) = HLiO (cr) + Ethanol (l)

By formula: C2H5LiO (cr) + H2O (l) = HLiO (cr) + C2H6O (l)

Quantity Value Units Method Reference Comment
Deltar-3.6 ± 2.5kJ/molRSCLeal and Martinho Simões, 1993 

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Blanchard, Joly, et al., 1974
Blanchard, J.M.; Joly, R.D.; Lettoffe, J.M.; Perachon, G.; Thourey, J., J. Chim. Phys. Phys.-Chim. Biol., 1974, 71, 472. [all data]

Leal and Martinho Simões, 1993
Leal, J.P.; Martinho Simões, J.A., J. Organometal. Chem., 1993, 460, 131. [all data]


Notes

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