LiOEt
- Formula: C2H5LiO
- Molecular weight: 52.002
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
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Individual Reactions
C2H5LiO (cr) + 0.5( • 1100
) (solution) = 0.5Li2O4S (solution) +
(solution)
By formula: C2H5LiO (cr) + 0.5(H2O4S • 1100H2O) (solution) = 0.5Li2O4S (solution) + C2H6O (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -27.15 ± 0.31 | kcal/mol | RSC | Blanchard, Joly, et al., 1974 | solvent: Sulphuric acid aqueous solution; The reaction enthalpy relies on -2.53 kcal/mol for the enthalpy of solution of EtOH(l) and on -17.5±0.3 for the enthalpy of solution of Li2SO4(cr) Blanchard, Joly, et al., 1974. |
C2H5LiO (cr) + ( • 552
) (solution) =
(l) +
(cr)
By formula: C2H5LiO (cr) + (HCl • 552H2O) (solution) = C2H6O (l) + ClLi (cr)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -10.1 ± 0.93 | kcal/mol | RSC | Leal and Martinho Simões, 1993 |
C2H5LiO (cr) + (l) = HLiO (cr) +
(l)
By formula: C2H5LiO (cr) + H2O (l) = HLiO (cr) + C2H6O (l)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -0.86 ± 0.60 | kcal/mol | RSC | Leal and Martinho Simões, 1993 |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Blanchard, Joly, et al., 1974
Blanchard, J.M.; Joly, R.D.; Lettoffe, J.M.; Perachon, G.; Thourey, J.,
J. Chim. Phys. Phys.-Chim. Biol., 1974, 71, 472. [all data]
Leal and Martinho Simões, 1993
Leal, J.P.; Martinho Simões, J.A.,
J. Organometal. Chem., 1993, 460, 131. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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