Cu2 anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas399. ± 21.kJ/molTherSpasov, Lee, et al., 20000 K dissociation energy
Δfgas399. ± 22.kJ/molR-EATaylor, Pettiettehall, et al., 1992EA set as 0.2 eV above onset to correct for unresolved hot bands.
Δfgas406. ± 16.kJ/molTherLeopold, Ho, et al., 1987Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Spasov, Lee, et al., 2000
Spasov, V.A.; Lee, T.H.; Ervin, K.M., Threshold collision-induced dissociation of anionic copper clusters and copper cluster monocarbonyls, J. Chem. Phys., 2000, 112, 4, 1713-1720, https://doi.org/10.1063/1.480736 . [all data]

Taylor, Pettiettehall, et al., 1992
Taylor, K.J.; Pettiettehall, C.L.; Cheshnovsky, O.; Smalley, R.E., Ultraviolet Photoelectron Spectra of Coinage Metal Clusters, J. Chem. Phys., 1992, 96, 4, 3319, https://doi.org/10.1063/1.461927 . [all data]

Leopold, Ho, et al., 1987
Leopold, D.G.; Ho, J.; Lineberger, W.C., Photoelectron Spectroscopy of Mass-selected Metal Cluster Anions. I. Cun-, n=1-10, J. Chem. Phys., 1987, 86, 4, 1715, https://doi.org/10.1063/1.452170 . [all data]


Notes

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