CF3CH2CH2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C3H4F3- + Hydrogen cation = Propane, 1,1,1-trifluoro-

By formula: C3H4F3- + H+ = C3H5F3

Quantity Value Units Method Reference Comment
Δr1699. ± 15.kJ/molCIDTGraul and Squires, 1990gas phase
Δr<1686.2kJ/molCIDTGraul and Squires, 1988gas phase
Quantity Value Units Method Reference Comment
Δr1667. ± 15.kJ/molH-TSGraul and Squires, 1990gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Graul and Squires, 1990
Graul, S.T.; Squires, R.R., Gas-Phase Acidities Derived from Threshold Energies for Activated Reactions, J. Am. Chem. Soc., 1990, 112, 7, 2517, https://doi.org/10.1021/ja00163a007 . [all data]

Graul and Squires, 1988
Graul, S.T.; Squires, R.R., On the Existence of Alkyl Carbanions in the Gas Phase, J. Am. Chem. Soc., 1988, 110, 2, 607, https://doi.org/10.1021/ja00210a054 . [all data]


Notes

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