LaCl3..Cl anion
- Formula: Cl4La-
- Molecular weight: 280.718
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -309.0 ± 4.1 | kcal/mol | Ther | Kudin, Vorob'ev, et al., 2007 | value altered from reference due to conversion from electron convention to ion convention |
| ΔfH°gas | -299.9 ± 3.6 | kcal/mol | Ther | Butman, Kudin, et al., 1987 | value altered from reference due to conversion from electron convention to ion convention |
Gas phase ion energetics data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
| EAneutral (eV) | Method | Reference | Comment |
|---|---|---|---|
| 7.03 ± 0.10 | LPES | Yang, Wang, et al., 2008 | Vertical Detachment Energy: 7.83±0.06 eV |
References
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kudin, Vorob'ev, et al., 2007
Kudin, L.S.; Vorob'ev, D.E.; Grishin, A.E.,
The Thermochemical Characteristics of the LnCl4- and Ln2Cl7- Negative Ions,
Russ. J. Phys. Chem., 2007, 81, 2, 147, https://doi.org/10.1134/S003602440702001X
. [all data]
Butman, Kudin, et al., 1987
Butman, M.F.; Kudin, L.S.; Burdukovskaya, G.G.; Krasnov, K.S.; Bozhko, N.V.,
Mass Spectrometric Determination of the Enthalpy of Formation of the Gaseous Ions LaCl4- and La2Cl7-,
Russ. J. Phys. Chem., 1987, 61, 1518. [all data]
Yang, Wang, et al., 2008
Yang, J.; Wang, X.-B.; Xing, X.-P.; Wang, L.-S.,
Photoelectron spectroscopy of anions at 118.2 nm: Observation of high electron binding energies in superhalogens MCl4- (M = Sc, Y, La),
J. Chem. Phys., 2008, 128, 20, 201102, https://doi.org/10.1063/1.2938390
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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