LaCl3..Cl anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-1293. ± 17.kJ/molTherKudin, Vorob'ev, et al., 2007value altered from reference due to conversion from electron convention to ion convention
Δfgas-1255. ± 15.kJ/molTherButman, Kudin, et al., 1987value altered from reference due to conversion from electron convention to ion convention

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
7.03 ± 0.10LPESYang, Wang, et al., 2008Vertical Detachment Energy: 7.83±0.06 eV

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Cl4La- + Cl3La = Cl7La2-

By formula: Cl4La- + Cl3La = Cl7La2-

Quantity Value Units Method Reference Comment
Δr239. ± 41.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention
Δr194. ± 34.kJ/molTDAsButman, Kudin, et al., 1987gas phase; value altered from reference due to conversion from electron convention to ion convention

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kudin, Vorob'ev, et al., 2007
Kudin, L.S.; Vorob'ev, D.E.; Grishin, A.E., The Thermochemical Characteristics of the LnCl4- and Ln2Cl7- Negative Ions, Russ. J. Phys. Chem., 2007, 81, 2, 147, https://doi.org/10.1134/S003602440702001X . [all data]

Butman, Kudin, et al., 1987
Butman, M.F.; Kudin, L.S.; Burdukovskaya, G.G.; Krasnov, K.S.; Bozhko, N.V., Mass Spectrometric Determination of the Enthalpy of Formation of the Gaseous Ions LaCl4- and La2Cl7-, Russ. J. Phys. Chem., 1987, 61, 1518. [all data]

Yang, Wang, et al., 2008
Yang, J.; Wang, X.-B.; Xing, X.-P.; Wang, L.-S., Photoelectron spectroscopy of anions at 118.2 nm: Observation of high electron binding energies in superhalogens MCl4- (M = Sc, Y, La), J. Chem. Phys., 2008, 128, 20, 201102, https://doi.org/10.1063/1.2938390 . [all data]


Notes

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