LaCl3..Cl anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-1293. ± 17.kJ/molTherKudin, Vorob'ev, et al., 2007value altered from reference due to conversion from electron convention to ion convention
Δfgas-1255. ± 15.kJ/molTherButman, Kudin, et al., 1987value altered from reference due to conversion from electron convention to ion convention

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Cl4La- + Cl3La = Cl7La2-

By formula: Cl4La- + Cl3La = Cl7La2-

Quantity Value Units Method Reference Comment
Δr239. ± 41.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention
Δr194. ± 34.kJ/molTDAsButman, Kudin, et al., 1987gas phase; value altered from reference due to conversion from electron convention to ion convention

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
7.03 ± 0.10LPESYang, Wang, et al., 2008Vertical Detachment Energy: 7.83±0.06 eV

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Cl4La- + Cl3La = Cl7La2-

By formula: Cl4La- + Cl3La = Cl7La2-

Quantity Value Units Method Reference Comment
Δr239. ± 41.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention
Δr194. ± 34.kJ/molTDAsButman, Kudin, et al., 1987gas phase; value altered from reference due to conversion from electron convention to ion convention

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kudin, Vorob'ev, et al., 2007
Kudin, L.S.; Vorob'ev, D.E.; Grishin, A.E., The Thermochemical Characteristics of the LnCl4- and Ln2Cl7- Negative Ions, Russ. J. Phys. Chem., 2007, 81, 2, 147, https://doi.org/10.1134/S003602440702001X . [all data]

Butman, Kudin, et al., 1987
Butman, M.F.; Kudin, L.S.; Burdukovskaya, G.G.; Krasnov, K.S.; Bozhko, N.V., Mass Spectrometric Determination of the Enthalpy of Formation of the Gaseous Ions LaCl4- and La2Cl7-, Russ. J. Phys. Chem., 1987, 61, 1518. [all data]

Yang, Wang, et al., 2008
Yang, J.; Wang, X.-B.; Xing, X.-P.; Wang, L.-S., Photoelectron spectroscopy of anions at 118.2 nm: Observation of high electron binding energies in superhalogens MCl4- (M = Sc, Y, La), J. Chem. Phys., 2008, 128, 20, 201102, https://doi.org/10.1063/1.2938390 . [all data]


Notes

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