(CO2)2 radical anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
2.790 ± 0.020LPESDeLuca, Niu, et al., 1988EA given is Vertical Detachment Energy. Adiabatic EA est as up to 1 eV smaller
>2.39999LPESBowen and Eaton, 1988Vertical Detachment Energy limit. Probably covalent oxalate

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

DeLuca, Niu, et al., 1988
DeLuca, M.J.; Niu, B.; Johnson, M.A., Photoelectron Spectroscopy of (CO2)n- Clusters with 2=n=13: Cluster Size Dependence of the Core Molecular Ion, J. Chem. Phys., 1988, 88, 9, 5857, https://doi.org/10.1063/1.454548 . [all data]

Bowen and Eaton, 1988
Bowen, K.H.; Eaton, J.G., Photodetachment Spectroscopy of Negative Cluster Ions, in The Structure of Small Molecules and Ions, Ed. R. Naaman, Z. Vager, Plenum NY, 1988, 1988, p.147-169. [all data]


Notes

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