2-furanyl-CH2 anion


Reaction thermochemistry data

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C5H5O- + Hydrogen cation = Furan, 2-methyl-

By formula: C5H5O- + H+ = C5H6O

Quantity Value Units Method Reference Comment
Δr1606. ± 13.kJ/molG+TSDePuy, Kass, et al., 1988gas phase; Anion of 2-methylfuran. Order: H2O<furan<2-Me-furan<MeOH.
Quantity Value Units Method Reference Comment
Δr1577. ± 13.kJ/molIMRBDePuy, Kass, et al., 1988gas phase; Anion of 2-methylfuran. Order: H2O<furan<2-Me-furan<MeOH.

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C5H5O- + Hydrogen cation = Furan, 2-methyl-

By formula: C5H5O- + H+ = C5H6O

Quantity Value Units Method Reference Comment
Δr1606. ± 13.kJ/molG+TSDePuy, Kass, et al., 1988gas phase; Anion of 2-methylfuran. Order: H2O<furan<2-Me-furan<MeOH.
Quantity Value Units Method Reference Comment
Δr1577. ± 13.kJ/molIMRBDePuy, Kass, et al., 1988gas phase; Anion of 2-methylfuran. Order: H2O<furan<2-Me-furan<MeOH.

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

DePuy, Kass, et al., 1988
DePuy, C.H.; Kass, S.R.; Bean, G.P., Formation and Reactions of Heteroaromatic Anions in the Gas Phase, J. Org. Chem., 1988, 53, 19, 4427, https://doi.org/10.1021/jo00254a001 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References