MoF4..F anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-1572. ± 23.kJ/molTherBorshchevskii, Boltalina, et al., 1988value altered from reference due to conversion from electron convention to ion convention

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
3.46 ± 0.18R-ABorshchevskii, Boltalina, et al., 1988value altered from reference due to conversion from electron convention to ion convention
3.47997R-ABorchevsky and Sidorov, 1985Fluoride Affinity: MoF4 > UF4 by 7.1 kcal/mol; value altered from reference due to conversion from electron convention to ion convention
>3.49948NBAECompton, Reinhardt, et al., 1978From MoF6
>3.30 ± 0.40NBAEMathur, Rothe, et al., 1977From MoF6

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Borshchevskii, Boltalina, et al., 1988
Borshchevskii, A.Ya.; Boltalina, O.V.; Sorokin, I.D.; Sidorov, L.N., Thermochemical Quantities for Gas Phase Iron, Uranium, and Molybdenum Fluorides, and Their Negative Ions., J. Chem. Thermodyn., 1988, 20, 5, 523, https://doi.org/10.1016/0021-9614(88)90080-8 . [all data]

Borchevsky and Sidorov, 1985
Borchevsky, A.Ya.; Sidorov, L.N., Ion-Molecule, Ion-Ion, and Molecule-Molecule Equilibria in the System Mo-U-Fe-F-O-e-, Dokl. Akad. Nauk SSSR Ser. Khim., 1985, 285, 377. [all data]

Compton, Reinhardt, et al., 1978
Compton, R.N.; Reinhardt, P.W.; Cooper, C.D., Collisional ionization between fast alkali atoms and selected hexafluoride molecules, J. Chem. Phys., 1978, 68, 2023. [all data]

Mathur, Rothe, et al., 1977
Mathur, B.P.; Rothe, R.W.; Reck, G.P., Ionization reactions of metal hexafluorides with alkali atoms and dimers, J. Chem. Phys., 1977, 67, 377. [all data]


Notes

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