(MeO)2PO anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C2H6O3P- + Hydrogen cation = Dimethyl phosphite

By formula: C2H6O3P- + H+ = C2H7O3P

Quantity Value Units Method Reference Comment
Δr1492. ± 15.kJ/molG+TSMcDonald, Chowdhury, et al., 1987gas phase; Acidity between MeNO2, EtSH. Acid taken as (MeO)2P(O)H.
Quantity Value Units Method Reference Comment
Δr1461. ± 15.kJ/molIMRBMcDonald, Chowdhury, et al., 1987gas phase; Acidity between MeNO2, EtSH. Acid taken as (MeO)2P(O)H.
Δr1469. ± 17.kJ/molIMRBAnderson, DePuy, et al., 1984gas phase; Between MeSH, H2S

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C2H6O3P- + Hydrogen cation = Dimethyl phosphite

By formula: C2H6O3P- + H+ = C2H7O3P

Quantity Value Units Method Reference Comment
Δr1492. ± 15.kJ/molG+TSMcDonald, Chowdhury, et al., 1987gas phase; Acidity between MeNO2, EtSH. Acid taken as (MeO)2P(O)H.
Quantity Value Units Method Reference Comment
Δr1461. ± 15.kJ/molIMRBMcDonald, Chowdhury, et al., 1987gas phase; Acidity between MeNO2, EtSH. Acid taken as (MeO)2P(O)H.
Δr1469. ± 17.kJ/molIMRBAnderson, DePuy, et al., 1984gas phase; Between MeSH, H2S

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

McDonald, Chowdhury, et al., 1987
McDonald, R.M.; Chowdhury, A.K.; Gung, W.Y.; DeWitt, K.D., Nucleophilic Reactivity in Anionic Ion-Molecule Reactions in Nucleophilicity, Harris, J.M, McManus, S.P. Eds., Amer. Chem. Soc, 1987. [all data]

Anderson, DePuy, et al., 1984
Anderson, D.R.; DePuy, C.H.; Filley, J.; Bierbaum, V.M., Gas Phase Chemistry of Trimethyl Phosphite, J. Am. Chem. Soc., 1984, 106, 22, 6513, https://doi.org/10.1021/ja00334a009 . [all data]


Notes

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