H2O..HCO3 anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-251.61kcal/molTherKeesee, Lee, et al., 1979 

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Clustering reactions

CHO3- + Water = CH3O4-

By formula: CHO3- + H2O = CH3O4-

Quantity Value Units Method Reference Comment
Δr15.70 ± 0.20kcal/molTDAsKeesee, Lee, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Δr8.50 ± 0.40kcal/molTDAsKeesee, Lee, et al., 1979gas phase

CH3O4- + 2Water = CH5O5-

By formula: CH3O4- + 2H2O = CH5O5-

Quantity Value Units Method Reference Comment
Δr14.90 ± 0.20kcal/molTDAsKeesee, Lee, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Δr6.2 ± 1.0kcal/molTDAsKeesee, Lee, et al., 1979gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Keesee, Lee, et al., 1979
Keesee, R.G.; Lee, N.; Castleman Jr., Properties of Clusters in the Gas Phase. 3. Hydration Complexes of CO3- and HCO3-, J. Am. Chem. Soc., 1979, 101, 10, 2599, https://doi.org/10.1021/ja00504a015 . [all data]


Notes

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