Benzene, 1-bromo-4-nitro- anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-8.3 ± 2.5kcal/molR-EAChowdhury, Heinis, et al., 1986ΔGea(423 K) = -29.0 kcal/mol; ΔSea (estimated) = -2.0 eu.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C6H4BrNO2- + Silicon tetrafluoride = C6H4BrF4NO2Si-

By formula: C6H4BrNO2- + F4Si = C6H4BrF4NO2Si-

Quantity Value Units Method Reference Comment
Δr11.70 ± 0.60kcal/molIMREWilliamson, Knighton, et al., 2001gas phase; at 150 C

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C6H4BrNO2- + Silicon tetrafluoride = C6H4BrF4NO2Si-

By formula: C6H4BrNO2- + F4Si = C6H4BrF4NO2Si-

Quantity Value Units Method Reference Comment
Δr11.70 ± 0.60kcal/molIMREWilliamson, Knighton, et al., 2001gas phase; at 150 C

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chowdhury, Heinis, et al., 1986
Chowdhury, S.; Heinis, T.; Grimsrud, E.P.; Kebarle, P., Entropy Changes and Electron Affinities from Gas-Phase Electron Transfer Equilibria: A- + B = A + B-, J. Phys. Chem., 1986, 90, 12, 2747, https://doi.org/10.1021/j100403a037 . [all data]

Williamson, Knighton, et al., 2001
Williamson, D.H.; Knighton, W.B.; Grimsrud, E.P., Lewis acid-base interactions of SiF4 with molecular anions formed by electron capture reactions, Int. J. Mass Spectrom., 2001, 206, 1-2, 53-61, https://doi.org/10.1016/S1387-3806(00)00388-2 . [all data]


Notes

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