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HCOS anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

CHOS- + Hydrogen cation = CH2OS

By formula: CHOS- + H+ = CH2OS

Quantity Value Units Method Reference Comment
Deltar1467. ± 13.kJ/molG+TSKass and DePuy, 1985gas phase; This acidity value, and the HOF(HCOSH), appear to have been estimates, and should not be taken as experimental ones - JEB, 2006,G3MP2B3: 334 kcal/mol
Quantity Value Units Method Reference Comment
Deltar1435. ± 13.kJ/molIMRBKass and DePuy, 1985gas phase; This acidity value, and the HOF(HCOSH), appear to have been estimates, and should not be taken as experimental ones - JEB, 2006,G3MP2B3: 334 kcal/mol

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kass and DePuy, 1985
Kass, S.R.; DePuy, C.H., Gas phase ion chemistry of azides. The generation of CH=N- and CH2=NCH2-, J. Org. Chem., 1985, 50, 2874. [all data]


Notes

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