CO3 radical anion

• Formula: CO₃^-
• Molecular weight: 60.0094
• Information on this page:
  • Gas phase thermochemistry data
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Ion clustering data
  • References
  • Notes
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CO₃^- +  = CH₂O₄^-

By formula: CO₃^- + H₂O = CH₂O₄^-

CO₃^- +  = C₂O₅^-

By formula: CO₃^- + CO₂ = C₂O₅^-

CO₃^- +  = C₃H₄O₅^-

By formula: CO₃^- + C₂H₄O₂ = C₃H₄O₅^-

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

CO₃^- +  = C₂O₅^-

By formula: CO₃^- + CO₂ = C₂O₅^-

CO₃^- +  = C₃H₄O₅^-

By formula: CO₃^- + C₂H₄O₂ = C₃H₄O₅^-

CO₃^- +  = CH₂O₄^-

By formula: CO₃^- + H₂O = CH₂O₄^-

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Keesee, Lee, et al., 1979
Keesee, R.G.; Lee, N.; Castleman Jr., Properties of Clusters in the Gas Phase. 3. Hydration Complexes of CO₃^- and HCO₃^-, J. Am. Chem. Soc., 1979, 101, 10, 2599, https://doi.org/10.1021/ja00504a015 . [all data]

Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E., Laboratory studies of negative ion reactions with atmospheric trace constituents, J. Chem. Phys., 1974, 61, 3181. [all data]

Smith, Lee, et al., 1978
Smith, G.P.; Lee, L.C.; Cosby, P.C.; Peterson, J.R.; Moseley, J.T., Photodissociation and photodetachment of molecular negative ions. V. Atmospheric ions from 7000 to 8400 A), J. Chem. Phys., 1978, 68, 3818. [all data]

Hiraoka and Yamabe, 1992
Hiraoka, K.; Yamabe, S., Formation of the Chelate Bonds in the Cluster O2(-)(CO2)n, CO3(-)(CO2)n, and NO2(-)(CO2)n, J. Chem. Phys., 1992, 97, 1, 643, https://doi.org/10.1063/1.463560 . [all data]

Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr., Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions, J. Chem. Phys., 1980, 73, 2195. [all data]

Viidanoja, Reiner, et al., 1998
Viidanoja, J.; Reiner, T.; Arnold, F., Laboratory Investigations of Negative Ion-Molecule Reactions of Formic and Acetic Acid., Int. J. Mass Spectrom., 1998, 181, 1-3, 31, https://doi.org/10.1016/S1387-3806(98)14151-9 . [all data]

Hunton, Hofmann, et al., 1985
Hunton, D.E.; Hofmann, M.; Lindeman, T.G.; Castleman, A.W., Photodissociation Dynamics of CO₃^-, J. Chem. Phys., 1985, 82, 1, 134, https://doi.org/10.1063/1.448786 . [all data]

Novich, Engelking, et al., 1979
Novich, S.E.; Engelking, P.C.; Jones, P.L.; Futrell, J.H.; Lineberger, W.C., Laser photoelectron, photodetachment, and photodestruction spectra of O₃-, J. Chem. Phys., 1979, 70, 2652. [all data]

Tiernan and Wu, 1978
Tiernan, T.O.; Wu, R.L.C., Thermochemical Data for Molecular Negative Ions from Collisional Dissociation Thresholds, Adv. Mass Spectrom., 1978, 7A, 136. [all data]

Vestal and Mauclaire, 1977
Vestal, M.L.; Mauclaire, G.H., Photodissociaton of negative ions formed in CO₂ and CO₂/O₂ Mixtures, J. Chem. Phys., 1977, 67, 3758. [all data]

Dotan, Davidson, et al., 1977
Dotan, I.; Davidson, J.A.; Streit, G.E.; Albritton, D.L.; Fehsenfeld, F.C., A study of the reaction O₃^- + CO₂ = CO₃^- + O₂ and its implication on the thermochemistry of CO₃ and O₃ and their negative ions, J. Chem. Phys., 1977, 67, 2874. [all data]

Hong, Woo, et al., 1977
Hong, S.P.; Woo, S.B.; Helmy, E.M., Photodetachment of thermally relaxed CO₃-, Phys. Rev. A:, 1977, 15, 1563. [all data]

Burt, 1972
Burt, J.A., Photodetachment cross sections for CO₃- and its first hydrate, J. Chem. Phys., 1972, 57, 4649. [all data]

Snodgrass, Roehl, et al., 1990
Snodgrass, J.T.; Roehl, C.M.; Vankoppen, P.A.M.; Palke, W.E.; Bowers, M.T., Photodissociation of CO3(-) - Product Kinetic Energy Measurements As a Probe of Excited State Potential Surfaces and Dissociation Dynamics, J. Chem. Phys., 1990, 92, 10, 5935, https://doi.org/10.1063/1.458363 . [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References

• Symbols used in this document:
  

  EAneutral	Electron affinity of neutral species
  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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