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Fe(CO)5..HO anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Deltafgas-1127.1kJ/molTherSunderlin and Squires, 1993HO- transfer equilibrium to SO2. Structure thought ot be (CO)4Fe-CO2H
Deltafgas<-1075.3kJ/molIMRBLane, Lee, et al., 1984 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sunderlin and Squires, 1993
Sunderlin, L.S.; Squires, R.R., Energetics and Mechanism of the Thermal Decarboxylation of (CO)4FeCOOH- in the Gas Phase, J. Am. Chem. Soc., 1993, 115, 1, 337, https://doi.org/10.1021/ja00054a048 . [all data]

Lane, Lee, et al., 1984
Lane, K.R.; Lee, R.E.; Sallans, L.; Squires, R.R., Formation and reactivity of Fe(CO)4COOH- in the gas phase. Implication for the Fe(CO)5 catalyzed water gas shift reaction, J. Am. Chem. Soc., 1984, 106, 5767. [all data]


Notes

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