CH2=Si(Me)CH2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C3H7Si- + Hydrogen cation = 2-Silaisobutene

By formula: C3H7Si- + H+ = C3H8Si

Quantity Value Units Method Reference Comment
Δr1613. ± 21.kJ/molG+TSDamrauer, DePuy, et al., 1986gas phase; Between H2O, MeOH
Quantity Value Units Method Reference Comment
Δr1586. ± 21.kJ/molIMRBDamrauer, DePuy, et al., 1986gas phase; Between H2O, MeOH

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C3H7Si- + Hydrogen cation = 2-Silaisobutene

By formula: C3H7Si- + H+ = C3H8Si

Quantity Value Units Method Reference Comment
Δr1613. ± 21.kJ/molG+TSDamrauer, DePuy, et al., 1986gas phase; Between H2O, MeOH
Quantity Value Units Method Reference Comment
Δr1586. ± 21.kJ/molIMRBDamrauer, DePuy, et al., 1986gas phase; Between H2O, MeOH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Damrauer, DePuy, et al., 1986
Damrauer, R.; DePuy, C.H.; Davidson, I.M.T.; Hughes, K.J., Gas phase ion chemistry of dimethylsilene, Organometallics, 1986, 5, 2050. [all data]


Notes

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