SO2..SO2 radical anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-800.9 ± 1.2kJ/molTherKeesee, Lee, et al., 1980 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
1.910 ± 0.050LPDDresch, Kramer, et al., 1991Both dissociation and electron detachment?
1.90 ± 0.20LPESSnodgrass, Coe, et al., 1988Appears to be dissociation + electron detachment
<2.760 ± 0.020LPESTsukuda, Hirose, et al., 1997Stated electron affinity is the Vertical Detachment Energy
2.50 ± 0.20NBAEBowen, Liesegang, et al., 1983 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr., Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions, J. Chem. Phys., 1980, 73, 2195. [all data]

Dresch, Kramer, et al., 1991
Dresch, T.; Kramer, H.; Thurner, Y.; Weber, R., Photoelectrons from Negative Dimers and Clusters of Sulfur Dioxide, Chem. Phys. Lett., 1991, 177, 4-5, 383, https://doi.org/10.1016/0009-2614(91)85070-D . [all data]

Snodgrass, Coe, et al., 1988
Snodgrass, J.T.; Coe, J.V.; Friedhoff, C.B.; McHugh, K.M.; Bowen, K.H., On the Photodissociation of (SO2)2-, J. Chem. Phys., 1988, 88, 12, 8014, https://doi.org/10.1063/1.454261 . [all data]

Tsukuda, Hirose, et al., 1997
Tsukuda, T.; Hirose, T.; Nagata, T., Electronic Structures of (SO2)n- as Studied by Photoelectron Spectroscopy, Int. J. Mass Spectrom. Ion Proc., 1997, 171, 1-3, 273, https://doi.org/10.1016/S0168-1176(97)00240-1 . [all data]

Bowen, Liesegang, et al., 1983
Bowen, K.H.; Liesegang, G.W.; Sanders, R.A.; Herschbach, D.W., Electron Attachment to Molecular Clusters by Collisional Charge Transfer, J. Phys. Chem., 1983, 87, 4, 557-565, https://doi.org/10.1021/j100227a009 . [all data]


Notes

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