SnI3 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

I3Sn- + Hydrogen cation = Triiodosilane

By formula: I3Sn- + H+ = HI3Si

Quantity Value Units Method Reference Comment
Δr274.60kcal/molN/ACheck, Faust, et al., 2001gas phase; NiO2-(q); ; ΔS(EA)=5.0
Quantity Value Units Method Reference Comment
Δr269.70kcal/molN/ACheck, Faust, et al., 2001gas phase; NiO2-(q); ; ΔS(EA)=5.0

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
3.21 ± 0.10EIAEPabst, Margrave, et al., 1978From SnI4
3.20999EIAEPabst, Perry, et al., 1977From SnI4
3.92194N/ACheck, Faust, et al., 2001NiO2-(q); ; ΔS(EA)=5.0

Protonation reactions

I3Sn- + Hydrogen cation = Triiodosilane

By formula: I3Sn- + H+ = HI3Si

Quantity Value Units Method Reference Comment
Δr274.60kcal/molN/ACheck, Faust, et al., 2001gas phase; NiO2-(q); ; ΔS(EA)=5.0
Quantity Value Units Method Reference Comment
Δr269.70kcal/molN/ACheck, Faust, et al., 2001gas phase; NiO2-(q); ; ΔS(EA)=5.0

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S., Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l . [all data]

Pabst, Margrave, et al., 1978
Pabst, R.E.; Margrave, J.L.; Franklin, J.L., Energy distribution in the products of ionic decomposition, Adv. Mass Spectrom., 1978, 7, 1217. [all data]

Pabst, Perry, et al., 1977
Pabst, R.E.; Perry, D.L.; Margrave, J.L.; Franklin, J.L., Electron impact studies of tin tetrahalides SnCl4, SnBr4 and SnI4, Int. J. Mass Spectrom. Ion Phys., 1977, 24, 323. [all data]


Notes

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