CF3SO3 anion

• Formula: CF₃O₃S^-
• Molecular weight: 149.070
• Information on this page:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Ion clustering data
  • References
  • Notes
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CF₃O₃S^- +  = CHF₃O₃S

By formula: CF₃O₃S^- + H⁺ = CHF₃O₃S

(CF₃O₃S^- • ) +  = (CF₃O₃S^- • 2)

By formula: (CF₃O₃S^- • H₂O) + H₂O = (CF₃O₃S^- • 2H₂O)

CF₃O₃S^- +  = (CF₃O₃S^- • )

By formula: CF₃O₃S^- + H₂O = (CF₃O₃S^- • H₂O)

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

Protonation reactions

CF₃O₃S^- +  = CHF₃O₃S

By formula: CF₃O₃S^- + H⁺ = CHF₃O₃S

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

CF₃O₃S^- +  = (CF₃O₃S^- • )

By formula: CF₃O₃S^- + H₂O = (CF₃O₃S^- • H₂O)

(CF₃O₃S^- • ) +  = (CF₃O₃S^- • 2)

By formula: (CF₃O₃S^- • H₂O) + H₂O = (CF₃O₃S^- • 2H₂O)

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Koppel, Taft, et al., 1994
Koppel, I.A.; Taft, R.W.; Anvia, F.; Zhu, S.Z.; Hu, L.Q.; Sung, K.S.; Desmarteau, D.D.; Yagupolskii, L.M., The Gas-Phase Acidities of Very Strong Neutral Bronsted Acids, J. Am. Chem. Soc., 1994, 116, 7, 3047, https://doi.org/10.1021/ja00086a038 . [all data]

Leito, Raamat, et al., 2009
Leito, I.; Raamat, E.; Kutt, A.; Saame, J.; Kipper, K.; Koppel, I.A.; Koppel, I.; Zhang, M.; Mishima, M.; Yagupolskii, L.M.; Garlyauskayte, R.Y.; Filatov, A.A., Revision of the Gas-Phase Acidity Scale below 300 kcal mol(-1), J. Phys. Chem. A, 2009, 113, 29, 8421-8424, https://doi.org/10.1021/jp903780k . [all data]

Adams, Smith, et al., 1986
Adams, N.G.; Smith, D.; Viggiano, A.A.; Paulson, J.F.; Henchman, M.J., Dissociative attachment reactions of electron with strong acid molecules, J. Chem. Phys., 1986, 84, 6728. [all data]

Viggiano, Henchman, et al., 1992
Viggiano, A.A.; Henchman, M.J.; Dale, F.; Deakyne, C.A.; Paulson, J.F., Gas-Phase Reactions of Weak Bronsted Bases I-, PO3-, HSO4-, FSO3-, and CF3SO3- with Strong Bronsted Acids H2SO4, FSO3H, and CF3SO3H - A Quantitative Study, J. Am. Chem. Soc., 1992, 114, 11, 4299, https://doi.org/10.1021/ja00037a039 . [all data]

Blades, Klassen, et al., 1995
Blades, A.T.; Klassen, J.S.; Kebarle, P., Free Energies of Hydration in the Gas Phase on the Anions of Some Oxo Acids of C, N, S, P, Cl and I, J. Am. Chem. Soc., 1995, 117, 42, 10563, https://doi.org/10.1021/ja00147a019 . [all data]

Herd, Misth, et al., 1989
Herd, C.A.; Misth, D.; Adams, N.G., A Study of Dissociative Electron Attachment to CF3SO3CH3 and CF3SO3C2H5 Triflate Esters Using the FALP Apparatus, Int. J. Mass Spectrom. Ion Proc., 1989, 91, 2, 177, https://doi.org/10.1016/0168-1176(89)83007-1 . [all data]

Viggiano, Paulson, et al., 1987
Viggiano, A.A.; Paulson, J.F.; Dale, F.; Henchman, M., Negative Ion Chemistry of Triflic Anhydride in the Gas Phase and the Electron Affinity of CF3SO3, J. Phys. Chem., 1987, 91, 11, 3031, https://doi.org/10.1021/j100295a077 . [all data]

Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References

• Symbols used in this document:
  

  EAneutral	Electron affinity of neutral species
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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