SnCl3 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

Cl3Sn- + Hydrogen cation = HCl3Sn

By formula: Cl3Sn- + H+ = HCl3Sn

Quantity Value Units Method Reference Comment
Δr1208.3kJ/molN/ACheck, Faust, et al., 2001gas phase; NiCl3-; ; ΔS(EA)=4.9
Quantity Value Units Method Reference Comment
Δr1173.2kJ/molN/ACheck, Faust, et al., 2001gas phase; NiCl3-; ; ΔS(EA)=4.9

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
3.40 ± 0.20NBAELacmann, Maneira, et al., 1983From SnCl4
3.69 ± 0.50NBAEMathur, Rothe, et al., 1979From SnCl4
2.500 ± 0.010EIAEPabst, Margrave, et al., 1978From SnCl4
2.52999EIAEPabst, Perry, et al., 1977From SnCl4
4.14908N/ACheck, Faust, et al., 2001NiCl3-; ; ΔS(EA)=4.9

Protonation reactions

Cl3Sn- + Hydrogen cation = HCl3Sn

By formula: Cl3Sn- + H+ = HCl3Sn

Quantity Value Units Method Reference Comment
Δr1208.3kJ/molN/ACheck, Faust, et al., 2001gas phase; NiCl3-; ; ΔS(EA)=4.9
Quantity Value Units Method Reference Comment
Δr1173.2kJ/molN/ACheck, Faust, et al., 2001gas phase; NiCl3-; ; ΔS(EA)=4.9

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S., Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l . [all data]

Lacmann, Maneira, et al., 1983
Lacmann, K.; Maneira, M.J.P.; Moutinho, A.M.C.; Weigman, U., Total and Double Differential Cross Sections of Ion- Pair Formations in Collisions of K Atoms with SnCl4 and CCl4, J. Chem. Phys., 1983, 78, 1767. [all data]

Mathur, Rothe, et al., 1979
Mathur, E.P.; Rothe, E.W.; Reck, G.P., Negative ions from the reactions of alkalis with SnCl4, GeCl4, and TiCl4, Int. J. Mass Spectrom. Ion Phys., 1979, 31, 77. [all data]

Pabst, Margrave, et al., 1978
Pabst, R.E.; Margrave, J.L.; Franklin, J.L., Energy distribution in the products of ionic decomposition, Adv. Mass Spectrom., 1978, 7, 1217. [all data]

Pabst, Perry, et al., 1977
Pabst, R.E.; Perry, D.L.; Margrave, J.L.; Franklin, J.L., Electron impact studies of tin tetrahalides SnCl4, SnBr4 and SnI4, Int. J. Mass Spectrom. Ion Phys., 1977, 24, 323. [all data]


Notes

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