SnCl3 anion
- Formula: Cl3Sn-
- Molecular weight: 225.070
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
EAneutral (eV) | Method | Reference | Comment |
---|---|---|---|
3.40 ± 0.20 | NBAE | Lacmann, Maneira, et al., 1983 | From SnCl4 |
3.69 ± 0.50 | NBAE | Mathur, Rothe, et al., 1979 | From SnCl4 |
2.500 ± 0.010 | EIAE | Pabst, Margrave, et al., 1978 | From SnCl4 |
2.52999 | EIAE | Pabst, Perry, et al., 1977 | From SnCl4 |
4.14908 | N/A | Check, Faust, et al., 2001 | NiCl3-; ; ΔS(EA)=4.9 |
Protonation reactions
Cl3Sn- + = HCl3Sn
By formula: Cl3Sn- + H+ = HCl3Sn
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 288.80 | kcal/mol | N/A | Check, Faust, et al., 2001 | gas phase; NiCl3-; ; ΔS(EA)=4.9 |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 280.40 | kcal/mol | N/A | Check, Faust, et al., 2001 | gas phase; NiCl3-; ; ΔS(EA)=4.9 |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lacmann, Maneira, et al., 1983
Lacmann, K.; Maneira, M.J.P.; Moutinho, A.M.C.; Weigman, U.,
Total and Double Differential Cross Sections of Ion- Pair Formations in Collisions of K Atoms with SnCl4 and CCl4,
J. Chem. Phys., 1983, 78, 1767. [all data]
Mathur, Rothe, et al., 1979
Mathur, E.P.; Rothe, E.W.; Reck, G.P.,
Negative ions from the reactions of alkalis with SnCl4, GeCl4, and TiCl4,
Int. J. Mass Spectrom. Ion Phys., 1979, 31, 77. [all data]
Pabst, Margrave, et al., 1978
Pabst, R.E.; Margrave, J.L.; Franklin, J.L.,
Energy distribution in the products of ionic decomposition,
Adv. Mass Spectrom., 1978, 7, 1217. [all data]
Pabst, Perry, et al., 1977
Pabst, R.E.; Perry, D.L.; Margrave, J.L.; Franklin, J.L.,
Electron impact studies of tin tetrahalides SnCl4, SnBr4 and SnI4,
Int. J. Mass Spectrom. Ion Phys., 1977, 24, 323. [all data]
Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S.,
Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements,
J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l
. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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