DOO anion
- Formula: DO2-
- Molecular weight: 34.0135
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
DO2- + = D2O2
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1571.8 ± 3.5 | kJ/mol | D-EA | Oakes, Harding, et al., 1985 | gas phase; Acid: DOOH -> DOO- + H+ |
| ΔrH° | 1580. ± 5.0 | kJ/mol | D-EA | Oakes, Harding, et al., 1985 | gas phase; For DOOD -> DOO- + D+. BDE: 89.0 Gurvich, Veyts, et al.; ΔSacid: 24.7 |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1544.1 ± 3.9 | kJ/mol | H-TS | Oakes, Harding, et al., 1985 | gas phase; Acid: DOOH -> DOO- + H+ |
| ΔrG° | 1549. ± 5.4 | kJ/mol | H-TS | Oakes, Harding, et al., 1985 | gas phase; For DOOD -> DOO- + D+. BDE: 89.0 Gurvich, Veyts, et al.; ΔSacid: 24.7 |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
| EAneutral (eV) | Method | Reference | Comment |
|---|---|---|---|
| 1.0770 ± 0.0050 | LPES | Ramond, Blanksby, et al., 2002 | |
| 1.089 ± 0.017 | LPES | Oakes, Harding, et al., 1985 | Acid: DOOH -> DOO- + H+ |
| 1.089 ± 0.017 | LPES | Oakes, Harding, et al., 1985 | For DOOD -> DOO- + D+. BDE: 89.0 Gurvich, Veyts, et al.; ΔSacid: 24.7 |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Oakes, Harding, et al., 1985
Oakes, J.M.; Harding, L.B.; Ellison, G.B.,
The photoelectron spectroscopy of HO2-,
J. Chem. Phys., 1985, 83, 5400. [all data]
Gurvich, Veyts, et al.
Gurvich, L.V.; Veyts, I.V.; Alcock, C.B.,
Hemisphere Publishing, NY, 1989, V. 1 2, Thermodynamic Properties of Individual Substances, 4th Ed. [all data]
Ramond, Blanksby, et al., 2002
Ramond, T.M.; Blanksby, S.J.; Kato, S.; Bierbaum, V.M.; Davico, G.E.; Schwartz, R.L.; Lineberger, W.C.; Elliso,
Heat of formation of the hydroperoxyl radical HOO via negative ion studies,
J. Phys. Chem. A, 2002, 106, 42, 9641-9647, https://doi.org/10.1021/jp014614h
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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