HSO4 anion

• Formula: HO₄S^-
• Molecular weight: 97.071
• Information on this page:
  • Gas phase ion energetics data
  • Ion clustering data
  • References
  • Notes
• Other data available:
  • Reaction thermochemistry data
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

Protonation reactions

HO₄S^- +  =

By formula: HO₄S^- + H⁺ = H₂O₄S

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

HO₄S^- +  = (HO₄S^- • )

By formula: HO₄S^- + HCl = (HO₄S^- • HCl)

(HO₄S^- • ) +  = (HO₄S^- • 2)

By formula: (HO₄S^- • HNO₃) + HNO₃ = (HO₄S^- • 2HNO₃)

Free energy of reaction

(HO₄S^- • ) + HO₃S = (HO₄S^- • HO₃S • )

By formula: (HO₄S^- • HNO₃) + HO₃S = (HO₄S^- • HO₃S • HNO₃)

Free energy of reaction

(HO₄S^- • ) +  = (HO₄S^- •  • )

By formula: (HO₄S^- • HNO₃) + H₂O = (HO₄S^- • H₂O • HNO₃)

Free energy of reaction

HO₄S^- + HO₃S = (HO₄S^- • HO₃S)

By formula: HO₄S^- + HO₃S = (HO₄S^- • HO₃S)

Free energy of reaction

HO₄S^- +  = (HO₄S^- • )

By formula: HO₄S^- + H₂O = (HO₄S^- • H₂O)

Bond type: Hydrogen bond (negative ion to hydride)

(HO₄S^- • ) +  = (HO₄S^- • 2)

By formula: (HO₄S^- • H₂O) + H₂O = (HO₄S^- • 2H₂O)

Bond type: Hydrogen bond (negative ion to hydride)

(HO₄S^- •  • 3) +  = (HO₄S^- • 2 • 3)

By formula: (HO₄S^- • H₂O • 3H₂O₄S) + H₂O = (HO₄S^- • 2H₂O • 3H₂O₄S)

Free energy of reaction

HO₄S^- +  = (HO₄S^- • )

By formula: HO₄S^- + H₂O₂ = (HO₄S^- • H₂O₂)

(HO₄S^- • 2) +  = (HO₄S^- •  • 2)

By formula: (HO₄S^- • 2H₂O₄S) + HNO₃ = (HO₄S^- • HNO₃ • 2H₂O₄S)

Free energy of reaction

(HO₄S^- • 3) +  = (HO₄S^- •  • 3)

By formula: (HO₄S^- • 3H₂O₄S) + HNO₃ = (HO₄S^- • HNO₃ • 3H₂O₄S)

Free energy of reaction

(HO₄S^- • 2) + HO₃S = (HO₄S^- • HO₃S • 2)

By formula: (HO₄S^- • 2H₂O₄S) + HO₃S = (HO₄S^- • HO₃S • 2H₂O₄S)

Free energy of reaction

(HO₄S^- • 2) +  = (HO₄S^- •  • 2)

By formula: (HO₄S^- • 2H₂O₄S) + H₂O = (HO₄S^- • H₂O • 2H₂O₄S)

Free energy of reaction

(HO₄S^- • 3) +  = (HO₄S^- •  • 3)

By formula: (HO₄S^- • 3H₂O₄S) + H₂O = (HO₄S^- • H₂O • 3H₂O₄S)

Free energy of reaction

(HO₄S^- • 4) +  = (HO₄S^- •  • 4)

By formula: (HO₄S^- • 4H₂O₄S) + H₂O = (HO₄S^- • H₂O • 4H₂O₄S)

Free energy of reaction

(HO₄S^- • ) +  = (HO₄S^- • 2)

By formula: (HO₄S^- • H₂O₄S) + H₂O₄S = (HO₄S^- • 2H₂O₄S)

Free energy of reaction

(HO₄S^- • 2) +  = (HO₄S^- • 3)

By formula: (HO₄S^- • 2H₂O₄S) + H₂O₄S = (HO₄S^- • 3H₂O₄S)

Free energy of reaction

(HO₄S^- • 3) +  = (HO₄S^- • 4)

By formula: (HO₄S^- • 3H₂O₄S) + H₂O₄S = (HO₄S^- • 4H₂O₄S)

Free energy of reaction

(HO₄S^- • 4) +  = (HO₄S^- • 5)

By formula: (HO₄S^- • 4H₂O₄S) + H₂O₄S = (HO₄S^- • 5H₂O₄S)

Free energy of reaction

HO₄S^- +  = (HO₄S^- • )

By formula: HO₄S^- + O₂S = (HO₄S^- • O₂S)

References

Go To: Top, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wang, Nicholas, et al., 2000
Wang, X.B.; Nicholas, J.B.; Wang, L.S., Photoelectron spectroscopy and theoretical calculations of SO4- and HSO4-: Confirmation of high electron affinities of SO4 and HSO4, J. Phys. Chem. A, 2000, 104, 3, 504-508, https://doi.org/10.1021/jp992726r . [all data]

Viggiano, Henchman, et al., 1992
Viggiano, A.A.; Henchman, M.J.; Dale, F.; Deakyne, C.A.; Paulson, J.F., Gas-Phase Reactions of Weak Bronsted Bases I-, PO3-, HSO4-, FSO3-, and CF3SO3- with Strong Bronsted Acids H2SO4, FSO3H, and CF3SO3H - A Quantitative Study, J. Am. Chem. Soc., 1992, 114, 11, 4299, https://doi.org/10.1021/ja00037a039 . [all data]

Vigiano, Perry, et al., 1980
Vigiano, A.A.; Perry, R.A.; Albritton, D.L.; Ferguson, E.E.; Fehsenfeld, F.C., The role of H₂SO₄ in stratospheric negative ion chemistry, J. Geophys. Res., 1980, 85, 4551. [all data]

House Jr. and Kemper, 1987
House Jr.; Kemper, K.A., Proton Affinities of Sulfate and Bisulfate Ions, J. Thermal Anal., 1987, 32, 6, 1855, https://doi.org/10.1007/BF01913977 . [all data]

Adams, Smith, et al., 1986
Adams, N.G.; Smith, D.; Viggiano, A.A.; Paulson, J.F.; Henchman, M.J., Dissociative attachment reactions of electron with strong acid molecules, J. Chem. Phys., 1986, 84, 6728. [all data]

Bohringer, Fahey, et al., 1984
Bohringer, H.; Fahey, D.W.; Fehsenfeld, F.C.; Ferguson, E.E., Bond energies of the molecules H₂O, SO₂, H₂O₂, and HCl to various atmospheric negative ions, J. Chem. Phys., 1984, 81, 2805. [all data]

Arnold, Viggiano, et al., 1982
Arnold, F.; Viggiano, A.A.; Schlager, H., Implications for Trace Gases and Aerosols of Large Negative Ions Clusters in the Stratosphere, Nature, 1982, 297, 5865, 371, https://doi.org/10.1038/297371a0 . [all data]

Arnold and Qiu, 1984
Arnold, F.; Qiu, S., Upper Stratosphere Negative Ion Composition Measurements and Infrared Trace Gas Abundances, Planet. Space Sci., 1984, 32, 2, 169, https://doi.org/10.1016/0032-0633(84)90151-X . [all data]

Blades, Klassen, et al., 1995
Blades, A.T.; Klassen, J.S.; Kebarle, P., Free Energies of Hydration in the Gas Phase on the Anions of Some Oxo Acids of C, N, S, P, Cl and I, J. Am. Chem. Soc., 1995, 117, 42, 10563, https://doi.org/10.1021/ja00147a019 . [all data]

Keesee and Castleman, 1986
Keesee, R.G.; Castleman, A.W., Jr., Thermochemical data on Ggs-phase ion-molecule association and clustering reactions, J. Phys. Chem. Ref. Data, 1986, 15, 1011. [all data]

Notes

Go To: Top, Gas phase ion energetics data, Ion clustering data, References

• Symbols used in this document:
  

  EAneutral	Electron affinity of neutral species
  T	Temperature
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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