Fe(CO)4 anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-160.9 ± 3.6kcal/molR-EANakajima, Taguwa, et al., 1994Vertical Detachment Energy: 3.02±0.13 eV

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C4FeO4- + Bromine = C4BrFeO4-

By formula: C4FeO4- + Br = C4BrFeO4-

Quantity Value Units Method Reference Comment
Δr>70.60kcal/molIMRBJones, McDonald, et al., 1989gas phase

C4FeO4- + Iodine atom = C4FeIO4-

By formula: C4FeO4- + I = C4FeIO4-

Quantity Value Units Method Reference Comment
Δr>55.00kcal/molIMRBJones, McDonald, et al., 1989gas phase

C4FeO4- + Chlorine atom = C4ClFeO4-

By formula: C4FeO4- + Cl = C4ClFeO4-

Quantity Value Units Method Reference Comment
Δr>70.30kcal/molIMRBJones, McDonald, et al., 1989gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C4FeO4- + Bromine = C4BrFeO4-

By formula: C4FeO4- + Br = C4BrFeO4-

Quantity Value Units Method Reference Comment
Δr>70.60kcal/molIMRBJones, McDonald, et al., 1989gas phase

C4FeO4- + Chlorine atom = C4ClFeO4-

By formula: C4FeO4- + Cl = C4ClFeO4-

Quantity Value Units Method Reference Comment
Δr>70.30kcal/molIMRBJones, McDonald, et al., 1989gas phase

C4FeO4- + Iodine atom = C4FeIO4-

By formula: C4FeO4- + I = C4FeIO4-

Quantity Value Units Method Reference Comment
Δr>55.00kcal/molIMRBJones, McDonald, et al., 1989gas phase

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nakajima, Taguwa, et al., 1994
Nakajima, A.; Taguwa, T.; Kaya, K., Photoelectron Spectroscopy of Iron Carbonyl Cluster Anions (Fen(CO)m(-), n=1-4), Chem. Phys. Lett., 1994, 221, 5-6, 436, https://doi.org/10.1016/0009-2614(94)00301-7 . [all data]

Jones, McDonald, et al., 1989
Jones, M.T.; McDonald, R.N.; Schell, P.L.; Ali, M.H., Kinetics and Mechanism of Halogen Atom Transfer Reactions between Haloalkanes and Several 17-Electron Transition Metal Complex Negative Ions in the Gas Phase, J. Am. Chem. Soc., 1989, 111, 16, 5983, https://doi.org/10.1021/ja00198a001 . [all data]


Notes

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