HCl..Cl anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-100.16kcal/molTherCaldwell and Kebarle, 1985 
Δfgas<-125. ± 12.kcal/molEIAEScheunemann, Illenberger, et al., 1980From CHCl3

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
4.896 ± 0.015LPESMetz, Kitsopoulos, et al., 1988Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Caldwell and Kebarle, 1985
Caldwell, G.; Kebarle, P., The hydrogen bond energies of the bihalide ions XHX- and YHX-, Can. J. Chem., 1985, 63, 1399. [all data]

Scheunemann, Illenberger, et al., 1980
Scheunemann, H.U.; Illenberger, E.; Baumgartel, H., Dissociative electron attachment to CCl4, CHCl3, CH2Cl2, and CH3Cl, Ber. Bunsen-Ges. Phys. Chem., 1980, 84, 580. [all data]

Metz, Kitsopoulos, et al., 1988
Metz, R.B.; Kitsopoulos, T.; Weaver, A.; Neumark, D.M., Study of the Transition State Region in the Cl+HCl Reaction by Photoelectron Spectroscopy of ClHCl-, J. Chem. Phys., 1988, 88, 2, 1463, https://doi.org/10.1063/1.454218 . [all data]


Notes

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