2-CN-bicyclo[2.2.2]octane-CO2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C10H12NO2- + Hydrogen cation = C10H13NO2

By formula: C10H12NO2- + H+ = C10H13NO2

Quantity Value Units Method Reference Comment
Δr335.9 ± 2.2kcal/molG+TSTaft, 1987gas phase; value altered from reference due to change in acidity scale
Quantity Value Units Method Reference Comment
Δr328.9 ± 2.0kcal/molIMRETaft, 1987gas phase; value altered from reference due to change in acidity scale

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
3.93 ± 0.16D-EATaft, 1987value altered from reference due to change in acidity scale

Protonation reactions

C10H12NO2- + Hydrogen cation = C10H13NO2

By formula: C10H12NO2- + H+ = C10H13NO2

Quantity Value Units Method Reference Comment
Δr335.9 ± 2.2kcal/molG+TSTaft, 1987gas phase; value altered from reference due to change in acidity scale
Quantity Value Units Method Reference Comment
Δr328.9 ± 2.0kcal/molIMRETaft, 1987gas phase; value altered from reference due to change in acidity scale

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Taft, 1987
Taft, R.W., The Nature and Analysis of Substitutent Electronic Effects, Personal communication. See also Prog. Phys. Org. Chem., 1987, 16, 1. [all data]


Notes

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