carbazolide anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C12H8N- + Hydrogen cation = Carbazole

By formula: C12H8N- + H+ = C12H9N

Quantity Value Units Method Reference Comment
Δr1444. ± 8.8kJ/molG+TSTaft and Bordwell, 1988gas phase
Δr1404. ± 21.kJ/molEIAEMuftakhov, Vasil'ev, et al., 1999gas phase
Quantity Value Units Method Reference Comment
Δr1412. ± 8.4kJ/molIMRETaft and Bordwell, 1988gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
2.65 ± 0.20D-EATaft and Bordwell, 1988 

Protonation reactions

C12H8N- + Hydrogen cation = Carbazole

By formula: C12H8N- + H+ = C12H9N

Quantity Value Units Method Reference Comment
Δr1444. ± 8.8kJ/molG+TSTaft and Bordwell, 1988gas phase
Δr1404. ± 21.kJ/molEIAEMuftakhov, Vasil'ev, et al., 1999gas phase
Quantity Value Units Method Reference Comment
Δr1412. ± 8.4kJ/molIMRETaft and Bordwell, 1988gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Taft and Bordwell, 1988
Taft, R.W.; Bordwell, F.G., Structural and Solvent Effects Evaluated from Acidities Measured in Dimethyl Sulfoxide and in the Gas Phase, Acc. Chem. Res., 1988, 21, 12, 463, https://doi.org/10.1021/ar00156a005 . [all data]

Muftakhov, Vasil'ev, et al., 1999
Muftakhov, M.V.; Vasil'ev, Y.V.; Khatymov, R.V.; Mazunov, V.A.; Takhistov, V.V.; Travkin, O.V.; Yakovleva, E.V., Thermochemistry of negatively charged ions. II. Energetics of formation of negative ions from acridanone and some of its derivatives, Rapid Commun. Mass Spectrom., 1999, 13, 10, 912-923, https://doi.org/10.1002/(SICI)1097-0231(19990530)13:10<912::AID-RCM585>3.0.CO;2-W . [all data]


Notes

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