2-methylenenorborn-5-en-3-ide anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C8H9- + Hydrogen cation = Bicyclo[2.2.1]hept-2-ene, 5-methylene-

By formula: C8H9- + H+ = C8H10

Quantity Value Units Method Reference Comment
Δr1632. ± 8.8kJ/molG+TSLee and Squires, 1986gas phase; Ca. 1 kcal < H2O
Quantity Value Units Method Reference Comment
Δr1603. ± 8.4kJ/molIMRBLee and Squires, 1986gas phase; Ca. 1 kcal < H2O

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C8H9- + Hydrogen cation = Bicyclo[2.2.1]hept-2-ene, 5-methylene-

By formula: C8H9- + H+ = C8H10

Quantity Value Units Method Reference Comment
Δr1632. ± 8.8kJ/molG+TSLee and Squires, 1986gas phase; Ca. 1 kcal < H2O
Quantity Value Units Method Reference Comment
Δr1603. ± 8.4kJ/molIMRBLee and Squires, 1986gas phase; Ca. 1 kcal < H2O

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lee and Squires, 1986
Lee, R.E.; Squires, R.R., Anionic homoaromaticity: A gas phase experimental study, J. Am. Chem. Soc., 1986, 105, 5078. [all data]


Notes

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