norbornenide anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

norbornenide anion + Hydrogen cation = 2-Norbornene

By formula: C7H9- + H+ = C7H10

Quantity Value Units Method Reference Comment
Δr1682. ± 13.kJ/molG+TSLee and Squires, 1986gas phase; Between NH3, EtNH2. Assigned as vinylic site by authors.
Quantity Value Units Method Reference Comment
Δr1648. ± 13.kJ/molIMRBLee and Squires, 1986gas phase; Between NH3, EtNH2. Assigned as vinylic site by authors.

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

norbornenide anion + Hydrogen cation = 2-Norbornene

By formula: C7H9- + H+ = C7H10

Quantity Value Units Method Reference Comment
Δr1682. ± 13.kJ/molG+TSLee and Squires, 1986gas phase; Between NH3, EtNH2. Assigned as vinylic site by authors.
Quantity Value Units Method Reference Comment
Δr1648. ± 13.kJ/molIMRBLee and Squires, 1986gas phase; Between NH3, EtNH2. Assigned as vinylic site by authors.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lee and Squires, 1986
Lee, R.E.; Squires, R.R., Anionic homoaromaticity: A gas phase experimental study, J. Am. Chem. Soc., 1986, 105, 5078. [all data]


Notes

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