norbornenide anion
- Formula: C7H9-
- Molecular weight: 93.1469
- IUPAC Standard InChI: InChI=1S/C7H9/c1-2-7-4-3-6(1)5-7/h1,6-7H,3-5H2/q-1
- IUPAC Standard InChIKey: SQRPSGZTPNZJQH-UHFFFAOYSA-N
- Chemical structure:
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
+
=
By formula: C7H9- + H+ = C7H10
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 402.1 ± 3.1 | kcal/mol | G+TS | Lee and Squires, 1986 | gas phase; Between NH3, EtNH2. Assigned as vinylic site by authors. |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 393.9 ± 3.0 | kcal/mol | IMRB | Lee and Squires, 1986 | gas phase; Between NH3, EtNH2. Assigned as vinylic site by authors. |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lee and Squires, 1986
Lee, R.E.; Squires, R.R.,
Anionic homoaromaticity: A gas phase experimental study,
J. Am. Chem. Soc., 1986, 105, 5078. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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