MeCO anion
- Formula: C2H3O-
- Molecular weight: 43.0452
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: C2H3O- + H+ = C2H4O
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 393.19 ± 0.96 | kcal/mol | D-EA | Nimlos, Soderquist, et al., 1989 | gas phase |
ΔrH° | 391.0 ± 2.1 | kcal/mol | G+TS | DePuy, Bierbaum, et al., 1985 | gas phase |
ΔrH° | 387.0 ± 8.0 | kcal/mol | CIDT | Graul and Squires, 1990 | gas phase |
ΔrH° | <382.00 | kcal/mol | CIDT | Graul and Squires, 1988 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 385.4 ± 1.1 | kcal/mol | H-TS | Nimlos, Soderquist, et al., 1989 | gas phase |
ΔrG° | 383.3 ± 2.0 | kcal/mol | IMRB | DePuy, Bierbaum, et al., 1985 | gas phase |
ΔrG° | <374.25 ± 0.60 | kcal/mol | H-TS | Graul and Squires, 1988 | gas phase |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Protonation reactions
By formula: C2H3O- + H+ = C2H4O
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 393.19 ± 0.96 | kcal/mol | D-EA | Nimlos, Soderquist, et al., 1989 | gas phase |
ΔrH° | 391.0 ± 2.1 | kcal/mol | G+TS | DePuy, Bierbaum, et al., 1985 | gas phase |
ΔrH° | 387.0 ± 8.0 | kcal/mol | CIDT | Graul and Squires, 1990 | gas phase |
ΔrH° | <382.00 | kcal/mol | CIDT | Graul and Squires, 1988 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 385.4 ± 1.1 | kcal/mol | H-TS | Nimlos, Soderquist, et al., 1989 | gas phase |
ΔrG° | 383.3 ± 2.0 | kcal/mol | IMRB | DePuy, Bierbaum, et al., 1985 | gas phase |
ΔrG° | <374.25 ± 0.60 | kcal/mol | H-TS | Graul and Squires, 1988 | gas phase |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Nimlos, Soderquist, et al., 1989
Nimlos, M.R.; Soderquist, J.A.; Ellison, G.B.,
Spectroscopy of CH3CO- and CH3CO,
J. Am. Chem. Soc., 1989, 111, 20, 7675, https://doi.org/10.1021/ja00202a001
. [all data]
DePuy, Bierbaum, et al., 1985
DePuy, C.H.; Bierbaum, V.M.; Damrauer, R.; Soderquist, J.A.,
Gas-phase reactions of the acetyl anion,
J. Am. Chem. Soc., 1985, 107, 3385. [all data]
Graul and Squires, 1990
Graul, S.T.; Squires, R.R.,
Gas-Phase Acidities Derived from Threshold Energies for Activated Reactions,
J. Am. Chem. Soc., 1990, 112, 7, 2517, https://doi.org/10.1021/ja00163a007
. [all data]
Graul and Squires, 1988
Graul, S.T.; Squires, R.R.,
On the Existence of Alkyl Carbanions in the Gas Phase,
J. Am. Chem. Soc., 1988, 110, 2, 607, https://doi.org/10.1021/ja00210a054
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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