MeCO anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C2H3O- + Hydrogen cation = Acetaldehyde

By formula: C2H3O- + H+ = C2H4O

Quantity Value Units Method Reference Comment
Δr393.19 ± 0.96kcal/molD-EANimlos, Soderquist, et al., 1989gas phase
Δr391.0 ± 2.1kcal/molG+TSDePuy, Bierbaum, et al., 1985gas phase
Δr387.0 ± 8.0kcal/molCIDTGraul and Squires, 1990gas phase
Δr<382.00kcal/molCIDTGraul and Squires, 1988gas phase
Quantity Value Units Method Reference Comment
Δr385.4 ± 1.1kcal/molH-TSNimlos, Soderquist, et al., 1989gas phase
Δr383.3 ± 2.0kcal/molIMRBDePuy, Bierbaum, et al., 1985gas phase
Δr<374.25 ± 0.60kcal/molH-TSGraul and Squires, 1988gas phase

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C2H3O- + Hydrogen cation = Acetaldehyde

By formula: C2H3O- + H+ = C2H4O

Quantity Value Units Method Reference Comment
Δr393.19 ± 0.96kcal/molD-EANimlos, Soderquist, et al., 1989gas phase
Δr391.0 ± 2.1kcal/molG+TSDePuy, Bierbaum, et al., 1985gas phase
Δr387.0 ± 8.0kcal/molCIDTGraul and Squires, 1990gas phase
Δr<382.00kcal/molCIDTGraul and Squires, 1988gas phase
Quantity Value Units Method Reference Comment
Δr385.4 ± 1.1kcal/molH-TSNimlos, Soderquist, et al., 1989gas phase
Δr383.3 ± 2.0kcal/molIMRBDePuy, Bierbaum, et al., 1985gas phase
Δr<374.25 ± 0.60kcal/molH-TSGraul and Squires, 1988gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nimlos, Soderquist, et al., 1989
Nimlos, M.R.; Soderquist, J.A.; Ellison, G.B., Spectroscopy of CH3CO- and CH3CO, J. Am. Chem. Soc., 1989, 111, 20, 7675, https://doi.org/10.1021/ja00202a001 . [all data]

DePuy, Bierbaum, et al., 1985
DePuy, C.H.; Bierbaum, V.M.; Damrauer, R.; Soderquist, J.A., Gas-phase reactions of the acetyl anion, J. Am. Chem. Soc., 1985, 107, 3385. [all data]

Graul and Squires, 1990
Graul, S.T.; Squires, R.R., Gas-Phase Acidities Derived from Threshold Energies for Activated Reactions, J. Am. Chem. Soc., 1990, 112, 7, 2517, https://doi.org/10.1021/ja00163a007 . [all data]

Graul and Squires, 1988
Graul, S.T.; Squires, R.R., On the Existence of Alkyl Carbanions in the Gas Phase, J. Am. Chem. Soc., 1988, 110, 2, 607, https://doi.org/10.1021/ja00210a054 . [all data]


Notes

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