CH2=C(NO)CH2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C3H4NO- + Hydrogen cation = C3H5NO

By formula: C3H4NO- + H+ = C3H5NO

Quantity Value Units Method Reference Comment
Δr385.6 ± 5.1kcal/molG+TSKass, Filley, et al., 1986gas phase; Between H2O, MeOH
Quantity Value Units Method Reference Comment
Δr379.0 ± 5.0kcal/molIMRBKass, Filley, et al., 1986gas phase; Between H2O, MeOH

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C3H4NO- + Hydrogen cation = C3H5NO

By formula: C3H4NO- + H+ = C3H5NO

Quantity Value Units Method Reference Comment
Δr385.6 ± 5.1kcal/molG+TSKass, Filley, et al., 1986gas phase; Between H2O, MeOH
Quantity Value Units Method Reference Comment
Δr379.0 ± 5.0kcal/molIMRBKass, Filley, et al., 1986gas phase; Between H2O, MeOH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kass, Filley, et al., 1986
Kass, S.R.; Filley, J.; Van Doren, J.M.; DePuy, C.H., Nitrous oxide in gas-phase ion-molecule chemistry: A versatile reagent for the determination of carbanion structure, J. Am. Chem. Soc., 1986, 108, 2849. [all data]


Notes

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