ICH2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

CH2I- + Hydrogen cation = Methane, iodo-

By formula: CH2I- + H+ = CH3I

Quantity Value Units Method Reference Comment
Δr386.3 ± 4.9kcal/molG+TSIngemann and Nibbering, 1985gas phase
Quantity Value Units Method Reference Comment
Δr379.4 ± 4.8kcal/molIMRBIngemann and Nibbering, 1985gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

CH2I- + Hydrogen cation = Methane, iodo-

By formula: CH2I- + H+ = CH3I

Quantity Value Units Method Reference Comment
Δr386.3 ± 4.9kcal/molG+TSIngemann and Nibbering, 1985gas phase
Quantity Value Units Method Reference Comment
Δr379.4 ± 4.8kcal/molIMRBIngemann and Nibbering, 1985gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ingemann and Nibbering, 1985
Ingemann, S.; Nibbering, N.M.M., Gas-phase acidity of CH3X [X = P(CH3)2, SCH3, F, Cl, Br, I] compounds, J. Chem. Soc. Perkin Trans. 2, 1985, 837. [all data]


Notes

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