ClO3 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(ClO3- • Water) + Water = (ClO3- • 2Water)

By formula: (ClO3- • H2O) + H2O = (ClO3- • 2H2O)

Quantity Value Units Method Reference Comment
Δr11.7 ± 1.5kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K
Quantity Value Units Method Reference Comment
Δr4.70 ± 0.30kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K

ClO3- + Hydrogen cation = HClO3

By formula: ClO3- + H+ = HClO3

Quantity Value Units Method Reference Comment
Δr313.2 ± 3.3kcal/molIMRBMeyer and Kass, 2010gas phase
Δr<311. ± 12.kcal/molD-EAAlekseev, Fedorova, et al., 1983gas phase; From ClO3F
Quantity Value Units Method Reference Comment
Δr306.9 ± 3.9kcal/molH-TSMeyer and Kass, 2010gas phase

ClO3- + Water = (ClO3- • Water)

By formula: ClO3- + H2O = (ClO3- • H2O)

Quantity Value Units Method Reference Comment
Δr13.2 ± 1.5kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K
Quantity Value Units Method Reference Comment
Δr6.20 ± 0.30kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

ClO3- + Hydrogen cation = HClO3

By formula: ClO3- + H+ = HClO3

Quantity Value Units Method Reference Comment
Δr313.2 ± 3.3kcal/molIMRBMeyer and Kass, 2010gas phase
Δr<311. ± 12.kcal/molD-EAAlekseev, Fedorova, et al., 1983gas phase; From ClO3F
Quantity Value Units Method Reference Comment
Δr306.9 ± 3.9kcal/molH-TSMeyer and Kass, 2010gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

ClO3- + Water = (ClO3- • Water)

By formula: ClO3- + H2O = (ClO3- • H2O)

Quantity Value Units Method Reference Comment
Δr13.2 ± 1.5kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K
Quantity Value Units Method Reference Comment
Δr6.20 ± 0.30kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K

(ClO3- • Water) + Water = (ClO3- • 2Water)

By formula: (ClO3- • H2O) + H2O = (ClO3- • 2H2O)

Quantity Value Units Method Reference Comment
Δr11.7 ± 1.5kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K
Quantity Value Units Method Reference Comment
Δr4.70 ± 0.30kcal/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Blades, Klassen, et al., 1995
Blades, A.T.; Klassen, J.S.; Kebarle, P., Free Energies of Hydration in the Gas Phase on the Anions of Some Oxo Acids of C, N, S, P, Cl and I, J. Am. Chem. Soc., 1995, 117, 42, 10563, https://doi.org/10.1021/ja00147a019 . [all data]

Meyer and Kass, 2010
Meyer, M.M.; Kass, S.R., Experimental and Theoretical Gas-Phase Acidities, Bond Dissociation Energies, and Heats of Formation of HClOx, x=1-4, J. Phys. Chem. A, 2010, 114, 12, 4086-4092, https://doi.org/10.1021/jp100888k . [all data]

Alekseev, Fedorova, et al., 1983
Alekseev, V.I.; Fedorova, L.I.; Baluev, A.V., Mass Spectrometric Study of Thermochemical Characteristics of Perchloryl Fluoride and its Decomposition Product Chlorosyl Fluoride, Izv. Akad. Nauk SSR Ser. Khim. 1084, 1983. [all data]


Notes

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