ClO3 anion

• Formula: ClO₃^-
• Molecular weight: 83.452
• Information on this page:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Ion clustering data
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

(ClO₃^- • ) +  = (ClO₃^- • 2)

By formula: (ClO₃^- • H₂O) + H₂O = (ClO₃^- • 2H₂O)

ClO₃^- +  = HClO₃

By formula: ClO₃^- + H⁺ = HClO₃

ClO₃^- +  = (ClO₃^- • )

By formula: ClO₃^- + H₂O = (ClO₃^- • H₂O)

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

ClO₃^- +  = HClO₃

By formula: ClO₃^- + H⁺ = HClO₃

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Blades, Klassen, et al., 1995
Blades, A.T.; Klassen, J.S.; Kebarle, P., Free Energies of Hydration in the Gas Phase on the Anions of Some Oxo Acids of C, N, S, P, Cl and I, J. Am. Chem. Soc., 1995, 117, 42, 10563, https://doi.org/10.1021/ja00147a019 . [all data]

Meyer and Kass, 2010
Meyer, M.M.; Kass, S.R., Experimental and Theoretical Gas-Phase Acidities, Bond Dissociation Energies, and Heats of Formation of HClOx, x=1-4, J. Phys. Chem. A, 2010, 114, 12, 4086-4092, https://doi.org/10.1021/jp100888k . [all data]

Alekseev, Fedorova, et al., 1983
Alekseev, V.I.; Fedorova, L.I.; Baluev, A.V., Mass Spectrometric Study of Thermochemical Characteristics of Perchloryl Fluoride and its Decomposition Product Chlorosyl Fluoride, Izv. Akad. Nauk SSR Ser. Khim. 1084, 1983. [all data]

Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References

• Symbols used in this document:
  

  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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