SiF4..F anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

F5Si- + Silicon tetrafluoride = F9Si2-

By formula: F5Si- + F4Si = F9Si2-

Quantity Value Units Method Reference Comment
Δr9.6 ± 2.0kcal/molIMREHiraoka, Nasu, et al., 2000gas phase
Quantity Value Units Method Reference Comment
Δr5.13kcal/molIMREHiraoka, Nasu, et al., 2000gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
>4.660 ± 0.020LPESKawamata, Neigishi, et al., 1996 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Nasu, et al., 2000
Hiraoka, K.; Nasu, M.; Minamitsu, A.; Shimizu, A.; Yamabe, S., On the structure and stability of gas-phase cluster ions SiF3+(CO)(n), SiF3OH2+(SiF4)(n), SiF4H+(SiF4)(n), and F- (SiF4)(n), J. Phys. Chem. A, 2000, 104, 36, 8353-8359, https://doi.org/10.1021/jp000525d . [all data]

Kawamata, Neigishi, et al., 1996
Kawamata, H.; Neigishi, Y.; Kishi, R.; Iwata, S.; Nakajima, A.; Kaya, K., Photoelectron Spectroscopy of Silicon-Fluorine Binary Cluster Anions (SinFm-), J. Chem. Phys., 1996, 105, 13, 5369, https://doi.org/10.1063/1.472377 . [all data]


Notes

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