CO2..Cl anion
- Formula: CClO2-
- Molecular weight: 79.463
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -649.23 | kJ/mol | Ther | Arnold, Bradforth, et al., 1995 | Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond. |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
| EAneutral (eV) | Method | Reference | Comment |
|---|---|---|---|
| 3.907 ± 0.010 | LPES | Arnold, Bradforth, et al., 1995 | Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond. |
| 3.960 ± 0.050 | LPES | Markovich, Giniger, et al., 1991 | Stated electron affinity is the Vertical Detachment Energy |
References
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Arnold, Bradforth, et al., 1995
Arnold, D.W.; Bradforth, S.E.; Kim, E.H.; Neumark, D.M.,
Study of halogen carbon dioxide clusters and the fluoroformyloxyl radical by photodetachment of X(-)(CO2) (X=I,Cl,Br) and FCO2-,
J. Chem. Phys., 1995, 102, 9, 3493, https://doi.org/10.1063/1.468575
. [all data]
Markovich, Giniger, et al., 1991
Markovich, G.; Giniger, R.; Levin, M.; Cheshnovsky, O.,
Photoelectron Spectroscopy of Iodine Anion Solvated in Water Clusters,
J. Chem. Phys., 1991, 95, 12, 9416, https://doi.org/10.1063/1.461172
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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