CO2..Cl anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-649.23kJ/molTherArnold, Bradforth, et al., 1995Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
3.907 ± 0.010LPESArnold, Bradforth, et al., 1995Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.
3.960 ± 0.050LPESMarkovich, Giniger, et al., 1991Stated electron affinity is the Vertical Detachment Energy

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Arnold, Bradforth, et al., 1995
Arnold, D.W.; Bradforth, S.E.; Kim, E.H.; Neumark, D.M., Study of halogen carbon dioxide clusters and the fluoroformyloxyl radical by photodetachment of X(-)(CO2) (X=I,Cl,Br) and FCO2-, J. Chem. Phys., 1995, 102, 9, 3493, https://doi.org/10.1063/1.468575 . [all data]

Markovich, Giniger, et al., 1991
Markovich, G.; Giniger, R.; Levin, M.; Cheshnovsky, O., Photoelectron Spectroscopy of Iodine Anion Solvated in Water Clusters, J. Chem. Phys., 1991, 95, 12, 9416, https://doi.org/10.1063/1.461172 . [all data]


Notes

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