MeCl..Cl anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-352.7kJ/molTherLi, Ross, et al., 1996 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CH3Cl2- + 2Chloromethane = C2H6Cl3-

By formula: CH3Cl2- + 2CH3Cl = C2H6Cl3-

Quantity Value Units Method Reference Comment
Δr46.44kJ/molN/AHiraoka, Mizuno, et al., 2001gas phase
Quantity Value Units Method Reference Comment
Δr16.5kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

CH3Cl2- + 2Chloromethane = C2H6Cl3-

By formula: CH3Cl2- + 2CH3Cl = C2H6Cl3-

Quantity Value Units Method Reference Comment
Δr46.44kJ/molN/AHiraoka, Mizuno, et al., 2001gas phase
Quantity Value Units Method Reference Comment
Δr16.5kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Li, Ross, et al., 1996
Li, C.; Ross, P.; Szulejko, J.; McMahon, T.B., High-Pressure Mass Spectrometric Investigations of the Potential Energy Surfaces of Gas-Phase Sn2 Reactions., J. Am. Chem. Soc., 1996, 118, 39, 9360, https://doi.org/10.1021/ja960565o . [all data]

Hiraoka, Mizuno, et al., 2001
Hiraoka, K.; Mizuno, T.; Iino, T.; Eguchi, D.; Yamabe, S., Characteristic changes of bond energies for gas-phase cluster ions of halide ions with methane and chloromethanes, J. Phys. Chem. A, 2001, 105, 20, 4887-4893, https://doi.org/10.1021/jp010143n . [all data]


Notes

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