Trichloromonofluoromethane
- Formula: CCl3F
- Molecular weight: 137.368
- IUPAC Standard InChIKey: CYRMSUTZVYGINF-UHFFFAOYSA-N
- CAS Registry Number: 75-69-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Methane, trichlorofluoro-; Algofrene Type 1; Arcton 9; Chlorofluoromethane (CCl3F); Electro-CF 11; F 11B; Fluorochloroform; Fluorotrichloromethane; Freon MF; Freon 11; Frigen 11; Frigen 11A; FC 11; FC 11, Halocarbon; FKW 11; Genetron 11; Isceon 131; Isotron 11; Kaltron 11; Ledon 11; Monofluorotrichloromethane; Propellant 11; R 11; R 11, Halocarbon; Trichlorofluoromethane; CFCl3; Fluorocarbon 11; Triclorofluormethane; CCl3F; Khladon 11; F 11; Halon 11; Refrigerant 11; Daiflon S 1; Daiflon 11; Arcton 11; Frigen S 11; Refrigerant R11; Distillex DS6; Methane, fluorotrichloro-; Chladone 11; Dymel 11; F 11 (halocarbon); Fluon 11; Freon 11A; Trichloromethyl fluoride; Trichlorofluorocarbon; Genetron 11SBA; fluorotrichloromethane (Freon 11)
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Gas phase thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -288.70 | kJ/mol | Review | Chase, 1998 | Data last reviewed in June, 1970 |
ΔfH°gas | -278. ± 8.8 | kJ/mol | Cm | Baibuz, 1961 | ALS |
ΔfH°gas | -268.3 ± 8.4 | kJ/mol | Ccb | Wartenberg and Schiefer, 1955 | Reanalyzed by Cox and Pilcher, 1970, Original value = -280. kJ/mol; ALS |
ΔfH°gas | -290. ± 20. | kJ/mol | Cm | Kirkbride and Davidson, 1954 | Von Wartenberg method; ALS |
Quantity | Value | Units | Method | Reference | Comment |
S°gas,1 bar | 309.74 | J/mol*K | Review | Chase, 1998 | Data last reviewed in June, 1970 |
Gas Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.
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Temperature (K) | 298. to 600. | 600. to 6000. |
---|---|---|
A | 34.06650 | 106.2694 |
B | 230.4309 | 1.245277 |
C | -289.4558 | -0.292652 |
D | 135.5248 | 0.022658 |
E | -0.232263 | -3.710084 |
F | -307.5847 | -331.8887 |
G | 292.6202 | 419.8728 |
H | -288.6964 | -288.6964 |
Reference | Chase, 1998 | Chase, 1998 |
Comment | Data last reviewed in June, 1970 | Data last reviewed in June, 1970 |
References
Go To: Top, Gas phase thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Baibuz, 1961
Baibuz, V.F.,
Explosion method and heat of formation of CF4, CFCl, CFCl3, and CCl4,
Dokl. Phys. Chem. (Engl. Transl.), 1961, 140, 786-788, In original 1358. [all data]
Wartenberg and Schiefer, 1955
Wartenberg, H.V.; Schiefer, J.,
Bildungswarmen von fluor-chlor-kohlenstoff-verbindungen,
Z. Anorg. Chem., 1955, 278, 326-332. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Kirkbride and Davidson, 1954
Kirkbride, F.W.; Davidson, F.G.,
Heats of formation of gaseous fluoro- and fluorochloro-carbons,
Nature (London), 1954, 174, 79-80. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, References
- Symbols used in this document:
S°gas,1 bar Entropy of gas at standard conditions (1 bar) ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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