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Bihlmeier, A.; Greene, T.M.; Himmel, H.-J., Toward a More Detailed Understanding of Oxidative-Addition Mechanisms: Combined Experimental and Quantum-Chemical Study of the Insertion of Titanium Atoms into C-H, Si-H, and Sn-H Bonds, Organomet., 2004, 23, 10, 2350, https://doi.org/10.1021/om040016o . [all data]

Bahlo, J.; Himmel, H.-J.; Schnockel, H., The First Dectection of Peroxo and Bis-superoxo Complexes of Aluminum: FAlO2 and FAlO4, Angew. Chem. Int. Ed., 2001, 40, 24, 4696, https://doi.org/10.1002/1521-3773(20011217)40:24<4696::AID-ANIE4696>3.0.CO;2-W . [all data]

Bahlo, J.; Himmel, H.-J.; Schnockel, H., Photolytic Reactions of Subvalent Aluminum(I) Halides in the Presence of Dioxygen: Generation and Characterization of the Peroxo Species XAlO, Inorg. Chem., 2002, 41, 10, 2678, https://doi.org/10.1021/ic011313d . [all data]

Bahlo, J.; Himmel, H.-J.; Schnockel, H., Characterization of the Side-On Coordinated Bissuperoxo Complexes of Aluminum FAl(O, Inorg. Chem., 2002, 41, 17, 4488, https://doi.org/10.1021/ic020208g . [all data]

Gaertner, B.; Himmel, H.-J., Characterization and Photochemistry of the Silane-Aluminum Complex Al•SiH, Angew. Chem. Int. Ed., 2002, 41, 9, 1538, https://doi.org/10.1002/1521-3773(20020503)41:9<1538::AID-ANIE1538>3.0.CO;2-K . [all data]

Gaertner, B.; Himmel, H.-J.; Macrae, V.A.; Downs, A.J.; Greene, T.M., Matrix Reactivity of Al and Ga Atoms (M) in the Presence of Silane: Generation and Characterization of theη2-Coordinated Complex M•SiH4, the Insertion Product HMSiH3, and the MI Species MSiH3 in a Solid Argon Matrix, Chem. Eur. J., 2004, 10, 14, 3430, https://doi.org/10.1002/chem.200305493 . [all data]

Gaertner, B.; Himmel, H.-J.; Macrae, V.A.; Pardoe, J.A.J.; Randall, P.G.; Downs, A.J., Some Novel Binuclear Group 13 Metal Tin Hydrides Formed in Ar Matrices Following the Codeposition of the Metal Vapor with SnH4, Chem. Eur. J., 2004, 10, 22, 5836, https://doi.org/10.1002/chem.200400564 . [all data]

Himmel, H.-J.; Bahlo, J.; Haussmann, M.; Kurth, F.; Stosser, G.; Schnockel, H., Matrix Reactivity of AlF and AlCl in the Presence of HCl and HBr: Generation and Characterization of the New Al(III) Hydrides HAlFCl, HAlFBr, and HAlClBr and the Monomeric Mixed Al(III) Halides AlX, Inorg. Chem., 2002, 41, 19, 4952, https://doi.org/10.1021/ic020275a . [all data]

Himmel, H.-J.; Downs, A.J.; Greene, T.M.; Andrews, L., Chem. Commun., 1999, 2243. [all data]

Himmel, H.-J.; Downs, A.J.; Greene, T.M., Formation and Characterization of the Indium Hydride Molecules H, J. Am. Chem. Soc., 2000, 122, 5, 922, https://doi.org/10.1021/ja9932333 . [all data]

Himmel, H.-J.; Downs, A.J.; Green, J.C.; Greene, T.M., Thermal and Photolytic Reactions of Gallium and Indium Atoms (M) and Their Dimers M, J. Phys. Chem. A, 2000, 104, 16, 3642, https://doi.org/10.1021/jp9938359 . [all data]

Himmel, H.-J.; Downs, A.J.; Greene, T.M.; Andrews, L., Matrix Photochemistry of Gallium and Indium Atoms (M) in the Presence of Methane: Formation and Characterization of the Divalent Species CH, Organomet., 2000, 19, 6, 1060, https://doi.org/10.1021/om990905p . [all data]

Himmel, H.-J.; Downs, A.J.; Greene, T.M., Chem. Commun., 2000, 871. [all data]

Himmel, H.-J.; Downs, A.J.; Greene, T.M., Thermal and Photochemical Reactions of Aluminum, Gallium, and Indium Atoms (M) in the Presence of Ammonia: Generation and Characterization of the Species M·NH, J. Am. Chem. Soc., 2000, 122, 40, 9793, https://doi.org/10.1021/ja001313x . [all data]

Himmel, H.-J.; Downs, A.J.; Greene, T.M., Reactions of Aluminum, Gallium, and Indium (M) Atoms with Phosphine: Generation and Characterization of the Species M·PH, Inorg. Chem., 2001, 40, 2, 396, https://doi.org/10.1021/ic000837v . [all data]

Himmel, H.-J.; Hubner, O.; Bischoff, F.A.; Klopper, W.; Manceron, L., Reactivity of titanium dimer and molecular nitrogen in rare gas matrices. Vibrational and electronic spectra and structure of Ti2N2, Phys. Chem. Chem. Phys., 2006, 8, 17, 2000, https://doi.org/10.1039/b517526g . [all data]

Himmel, H.-J.; Hubner, O.; Klopper, W.; Manceron, L., Cleavage of the N2 Triple Bond by the Ti Dimer: A Route to Molecular Materials for Dinitrogen Activation?, Angew. Chem. Int. Ed., 2006, 45, 17, 2799, https://doi.org/10.1002/anie.200503709 . [all data]

Himmel, H.-J., Reaction of AlCl Monomers with Acetylene in a Solid Argon Matrix at 12 K: First Characterization of the Aluminum Acetylide Species Cl(H)AlCCH, Featuring a Short Al-C Bond, Organomet., 2003, 22, 13, 2679, https://doi.org/10.1021/om030236m . [all data]

Himmel, H.-J., Eur. J. Inorg. Chem., 2003, 4087. [all data]

Himmel, H.-J., A Comparison of the Reactivity of Ni Atoms Toward CH4, SiH4, and SnH4: A Combined Matrix Isolation and Quantum-Chemical Study, Chem. Eur. J., 2004, 10, 11, 2851, https://doi.org/10.1002/chem.200305763 . [all data]

Himmel, H.-J.; Klaus, C., Photolytically Induced Reaction of Monomeric AlCl with Dihydrogen in a Solid Ar Matrix at 12 K: Generation and Characterization of the Previously Unknown Monomeric Aluminium Hydride ClAlH2, Z. Anorg. Allg. Chem., 2003, 629, 9, 1477, https://doi.org/10.1002/zaac.200300055 . [all data]

Himmel, H.-J.; Manceron, L.; Downs, A.J.; Pullumbi, P., Characterization and Photochemistry of the Gallium and Indium Subhydrides Ga2H2 and In2H2 This work was supported by the Deutsche Forschungsgemeinschaft (Habilitation grant to H.-J. H.), the CNRS (L. M.), and the EPSRC (A. J. D.)., Angew. Chem. Int. Ed., 2002, 41, 5, 796, https://doi.org/10.1002/1521-3773(20020301)41:5<796::AID-ANIE796>3.0.CO;2-3 . [all data]

Himmel, H.-J.; Manceron, L.; Downs, A.J.; Pullumbi, P., Formation and Characterization of the Gallium and Indium Subhydride Molecules Ga, J. Am. Chem. Soc., 2002, 124, 16, 4448, https://doi.org/10.1021/ja0122795 . [all data]

Kohn, A.; Gaertner, B.; Himmel, H.-J., On the Oxidation of Gallium and Indium: Characterization of the Cyclic and Linear GaO2 and InO2 Molecules Generated by the Spontaneous and Photoinduced Reaction of Ga and In Atoms with O2 and Determination of the Reaction Mechanism, Chem. Eur. J., 2005, 11, 19, 5575, https://doi.org/10.1002/chem.200500137 . [all data]

Kohn, A.; Himmel, H.-J.; Gaertner, B., Why Does a Ga2 Dimer React Spontaneously with H2, but a Ga Atom Does Not?---A Detailed Quantum Chemical Investigation of the Differences in Reactivity Between Ga Atoms and Ga2 Dimers, in Combination with Experimental Results, Chem. Eur. J., 2003, 9, 16, 3909, https://doi.org/10.1002/chem.200204633 . [all data]