GA4 MeTMS

• Formula: C₂₃H₃₄O₅Si
• Molecular weight: 418.5986
• IUPAC Standard InChI: InChI=1S/C23H34O5Si/c1-13-11-22-12-14(13)7-8-15(22)23-10-9-16(28-29(4,5)6)21(2,20(25)27-23)18(23)17(22)19(24)26-3/h14-18H,1,7-12H2,2-6H3/t14-,15?,16+,17?,18?,21-,22+,23-/m0/s1 Copy

  
• IUPAC Standard InChIKey: ATWIBZVZMYFKOI-JKQFYZDSSA-N Copy
• Chemical structure:
  This structure is also available as a 2d Mol file
• Stereoisomers:
  • GA7-isolactone, methyl ester TMS ether
  • [14C1]GA4 methyl ester TMS ether
  • 3-epi-GA63, MeTMS
  • 3-epi-GA4, MeTMS
  • epi-GA4, MeTMS
• Other names: GA4 methyl ester TMS ether; GA4, methyl ester TMS; Gibberelline GA4, methyl ester TMS ether; Gibberellin GA4, methyl ester trimethylsilyl ether
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Normal alkane RI, non-polar column, custom temperature program
  • References
  • Notes
• Other data available:
  • Gas Chromatography
• Options:
  • Switch to calorie-based units

Normal alkane RI, non-polar column, custom temperature program

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

References

Go To: Top, Normal alkane RI, non-polar column, custom temperature program, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Suzuki, Ishiyama, et al., 2005
Suzuki, H.; Ishiyama, K.; Kobayashi, M.; Ogawa, T., Specific expression of the gibberellin 3β -hydroxylase gene, HvGA3ox2, in the epithelium is important for Amy1 expression in germinating barley seeds, Plant Biotechnology, 2005, 22, 3, 195-200, https://doi.org/10.5511/plantbiotechnology.22.195 . [all data]

Chung, Kuo, et al., 2003
Chung, J.-D.; Kuo, S.-R.; Chien, C.-T., Identification and quantification of gibberellin transformation and dosage changes in good and poor flowering clones of Calocedrus formosana grafts, Taiwan J. For. Sci., 2003, 18, 4, 387-400. [all data]

Yamazaki, Nishijima, et al., 2002
Yamazaki, H.; Nishijima, T.; Koshioka, M.; Miura, H., Gibberellins do no act against abscisic acid in the regulation of bulb dormancy of Allium wakegi Araki, Plant Growth Regul., 2002, 36, 3, 223-229, https://doi.org/10.1023/A:1016577529378 . [all data]

Wang, Little, et al., 1996
Wang, Q.; Little, C.H.A.; Moritz, T.; Odén, P.C., Identification of endogenous gibberellins, and metabolism of tritiated and deuterated GA₄, GA₉, and GA₂₀, in Scots pine (Pinus sylvestris) shoots, Physiol. Plant., 1996, 97, 4, 764-771, https://doi.org/10.1111/j.1399-3054.1996.tb00542.x . [all data]

Kawaide, Sassa, et al., 1995
Kawaide, H.; Sassa, T.; Kamiya, Y., Plant-like biosynthesis of gibberellin A₁ in the fungus Phaeosphaeria Sp. L487, Phytochemistry, 1995, 39, 2, 305-310, https://doi.org/10.1016/0031-9422(95)00006-S . [all data]

Koshioka, Nishijama, et al., 1995
Koshioka, M.; Nishijama, T.; Mander, L.N., Gibberellin metabolism in suspension cultured cells of Raphanus Sativus, Phytochemistry, 1995, 38, 2, 359-363, https://doi.org/10.1016/0031-9422(94)00624-3 . [all data]

Tanno, Nakayama, et al., 1995
Tanno, N.; Nakayama, M.; Kurosawa, H.; Wakatsuki, M.; Tanno, M.; Abe, M.; Okagami, N.; Yokota, T., Endogenous gibberellins from three East Asian Stenophora species of the genus Dioscorea (Yams), Z. Naturforsch., 1995, 50c, 193-198. [all data]

Lange, Hedden, et al., 1993
Lange, T.; Hedden, P.; Graebe, J.E., Gibberellin biosynthesis in cell-free extracts from developing Cucurbita maxima embryos and the identification of new endogenous gibberellins, Planta, 1993, 189, 3, 350-358, https://doi.org/10.1007/BF00194431 . [all data]

Nishijima, Murakami, et al., 1993
Nishijima, T.; Murakami, F.; Koshioka, M.; Yamazaki, H., Endogenous gibberellins in Aralia cordata, Japan Society for Biosci. Biotechnol. Agrochem., 1993, 57, 1, 1953-1954, https://doi.org/10.1271/bbb.57.1953 . [all data]

Talon, Zacarias, et al., 1992
Talon, M.; Zacarias, L.; PRimo-Millo, E., Gibberellins and Partenocarpic ability in developing ovaries of seedless mandarins, Plant Physiol., 1992, 99, 4, 1575-1581, https://doi.org/10.1104/pp.99.4.1575 . [all data]

Matheussen, Morgan, et al., 1991
Matheussen, A.-M.; Morgan, P.W.; Frederiksen, R.A., Implication of gibberellins in head smut (Sporisorium reilianum) of Sorghum bicolor, Plant Physiol., 1991, 96, 2, 537-544, https://doi.org/10.1104/pp.96.2.537 . [all data]

Yamane, Fujioka, et al., 1988
Yamane, H.; Fujioka, S.; Spray, C.R.; Phinney, B.O.; MacMillan, J.; Gaskin, P.; Takahashi, N., Endogenous Gibberellines from Sporophytes of Two Tree Ferns, Cibotium glaucum and Dicksonia antarctica, Plant Phisiol., 1988, 86, 3, 857-862, https://doi.org/10.1104/pp.86.3.857 . [all data]

Notes

Go To: Top, Normal alkane RI, non-polar column, custom temperature program, References

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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