GA29, MeTMSi
- Formula: C26H42O6Si2
- Molecular weight: 506.7791
- IUPAC Standard InChIKey: AINOJINHOWCGRJ-NKPCIVKHSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: GA29 methyl ester TMS ether; GA29, Me-TMS; Gibberelline GA29, methyl ester TMS ether
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Van Den Dool and Kratz RI, non-polar column, custom temperature program
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | CP Sil 5 CB | DB-5 | DB-5 | CP Sil 5 CB | CP Sil 5 CB |
Column length (m) | 25. | 15. | 15. | 25. | 25. |
Carrier gas | He | He | He | ||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | ||||
Program | 60C (1min) => 20C/min => 170C => 4C/min => 290C | 60C(0.5min) => 20C/min => 200C => 5C/min => 300C | 60C(0.5min) => 20C/min => 200C => 5C/min => 300C | 60C(0.7min) => 20C/min => 220C => 4C/min => 300C | 60C(0.7min) => 20C/min => 220C => 4C/min => 300C |
I | 2722. | 2672. | 2672. | 2712. | 2712. |
Reference | Blake, Taylor, et al., 2002 | Pearce, Hutt, et al., 2002 | Pearce, Hutt, et al., 2002 | Taylor, Blake, et al., 2000 | Taylor, Blake, et al., 2000 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | CP-Sil5 CB MS | CP-Sil5 CB MS | OV-1 | BP-1 | BP-1 |
Column length (m) | 25. | 25. | 25. | 25. | 25. |
Carrier gas | He | He | |||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.2 | 0.2 | 0.2 |
Phase thickness (μm) | 0.25 | 0.1 | 0.1 | ||
Program | 90C(1min) => 20C/min => 220C => 4C/min => 290C | 90C(1min) => 20C/min => 220C => 4C/min => 290C | 60C(2min) => 10C/min => 150C => 3C/min => 300C | 60C(2min) => 10C/min => 150C => 3C/min => 300C | 60C(2min) => 10C/min => 150C => 3C/min => 300C |
I | 2684. | 2698. | 2684. | 2689. | 2689. |
Reference | Roberts, Blake, et al., 1999 | Roberts, Blake, et al., 1999 | Webb, Appleford, et al., 1998 | Webb, Appleford, et al., 1998 | Webb, Appleford, et al., 1998 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-1 | DB-1 | CP Sil 5 CB | CP Sil 5 CB | OV-1 |
Column length (m) | 30. | 30. | 30. | 30. | 25. |
Carrier gas | He | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.2 |
Phase thickness (μm) | 0.4 | 0.4 | 0.25 | ||
Program | 40C (2min) => 10C/min => 150C => 3C/min => 300C | 40C (2min) => 10C/min => 150C => 3C/min => 300C | 200C => 25C/min => 250C => 4C/min => 280C(4min) | 200C => 25C/min => 250C => 4C/min => 280C(4min) | 60C(2min) => 10min/C => 150C => 3C/min => 300C |
I | 2686. | 2690. | 2691. | 2691. | 2687. |
Reference | Grünzweig, Rabinowitch, et al., 1997 | Grünzweig, Rabinowitch, et al., 1997 | Kappers, Jordi, et al., 1997 | Kappers, Jordi, et al., 1997 | Spray, Kobayashi, et al., 1996 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-1 | DB-1 | OV-1 | OV-1 | OV-1 |
Column length (m) | 15. | 15. | 25. | 25. | 25. |
Carrier gas | He | He | He | ||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.2 | 0.2 | 0.2 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | |
Program | 60C(1min) => 20C/min => 200C => 4C/min => 260C | 60C(1min) => 20C/min => 200C => 4C/min => 260C | 60C(2min) => 10C/min => 150C => 3C/min => 300C | 60C(2min) => 10C/min => 150C => 3C/min => 300C | 60C(2min) => 13C/min => 150C => 3C/min => 280C(10min) |
I | 2679. | 2679. | 2684. | 2690. | 2690. |
Reference | Ridoutt, Pharis, et al., 1995 | Ridoutt, Pharis, et al., 1995 | Santes, Hedden, et al., 1995 | Santes, Hedden, et al., 1995 | Talo, Spray, et al., 1995 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | OV-1 | CP Sil 5 CB | BP-1 | BP-1 | OV-1 |
Column length (m) | 25. | 25. | 25. | 25. | 25. |
Carrier gas | He | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.2 | 0.25 | 0.22 | 0.22 | 0.2 |
Phase thickness (μm) | 0.25 | 0.25 | |||
Program | 60C(2min) => 13C/min => 150C => 3C/min => 280C(10min) | 50C(1min) => 15C/min => 220C => 2C/min => 300C | 60C => 30C/min => 240C => 3C/min => 290C | 60C => 30C/min => 240C => 3C/min => 290C | 60C(2min) => 13C/min => 150C => 3C/min => 280C(10min) |
I | 2690. | 2698. | 2695. | 2696. | 2688. |
Reference | Talo, Spray, et al., 1995 | Blake and Browning, 1994 | Hasan, Ridoutt, et al., 1994 | Hasan, Ridoutt, et al., 1994 | Kobayashi, Gaskin, et al., 1994 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-1 | CP Sil 5 CB | OV-1 | SPB-1 | SPB-1 |
Column length (m) | 15. | 25. | 25. | 30. | 30. |
Carrier gas | He | He | He | ||
Substrate | |||||
Column diameter (mm) | 0.22 | 0.25 | 0.22 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | |
Program | 60(0.1 min)-200 0C at 20 deg/min; 200-300 0C at 5 deg/min | 60C(0.3min) => 20C/min => 220C => 4C/min => 300C | 60C(2min) => 10C/min => 150C => 3C/min => 310C | 60C(2min) => 20C/min => 160C => 5C/min => 290C | 60C(2min) => 20C/min => 160C => 5C/min => 290C |
I | 2690. | 2699. | 2684. | 2694. | 2694. |
Reference | Pearce, Koshioka, et al., 1994 | Taylor, Blake, et al., 1994 | Waycott, Smith, et al., 1991 | Poling and Maier, 1988 | Poling and Maier, 1988 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary |
---|---|
Active phase | OV-1 |
Column length (m) | |
Carrier gas | He |
Substrate | |
Column diameter (mm) | |
Phase thickness (μm) | |
Program | 50C(1min) => 15C/min => 200C => 4C/min => 260C |
I | 2681. |
Reference | Heupel R.C., Phinney B.O., et al., 1985 |
Comment | MSDC-RI |
References
Go To: Top, Van Den Dool and Kratz RI, non-polar column, custom temperature program, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Blake, Taylor, et al., 2002
Blake, P.S.; Taylor, J.M.; Finch-Savage, W.E.,
Identification of abscisic acid, indole-3-acetic acid, jasmonic acid, indole-3-acetonitrile, methyl jasmonate and gibberellins in developing, dormant and startified seeds of ash (Fraxinus excelsior),
Plant Growth Regul., 2002, 37, 2, 119-125, https://doi.org/10.1023/A:1020504610172
. [all data]
Pearce, Hutt, et al., 2002
Pearce, D.W.; Hutt, O.E.; Rood, S.B.; Mander, L.N.,
Gibberellins in shoots and developing capsules of Populus species,
Phytochemistry, 2002, 59, 6, 679-687, https://doi.org/10.1016/S0031-9422(02)00009-2
. [all data]
Taylor, Blake, et al., 2000
Taylor, D.R.; Blake, P.S.; Crisp, C.M.,
Identification of gibberellins in leaf tissues of day-neutral strawberry (Fragaria × ananassa Duch.) cultivars,
Plant Growth Regul., 2000, 30, 1, 5-7, https://doi.org/10.1023/A:1006275024517
. [all data]
Roberts, Blake, et al., 1999
Roberts, A.V.; Blake, P.S.; Lewis, R.; Taylor, J.M.; Dunstan, D.I.,
The effect of gibberellins on flowering in roses,
J. Plant Growth Regul., 1999, 18, 3, 113-119, https://doi.org/10.1007/PL00007058
. [all data]
Webb, Appleford, et al., 1998
Webb, S.E.; Appleford, N.E.J.; Gaskin, P.; Lenton, J.R.,
Gibberellins in internodes and ears of wheat containing different dwarfing alleles,
Phytochemistry, 1998, 47, 5, 671-677, https://doi.org/10.1016/S0031-9422(97)00684-5
. [all data]
Grünzweig, Rabinowitch, et al., 1997
Grünzweig, J.M.; Rabinowitch, H.D.; Katan, J.; Wodner, M.; Ben-Tal, Y.,
Endogenous gibberellins in foliage of tomato (Lycopersicon esculentum),
Phytochemistry, 1997, 46, 5, 811-815, https://doi.org/10.1016/S0031-9422(97)00383-X
. [all data]
Kappers, Jordi, et al., 1997
Kappers, I.F.; Jordi, W.; Maas, F.M.; van der Plas, L.H.W.,
Gibberellins in leaves of Alstroemeria hybrida: identification and quantification in relation to leaf age,
J. Plant Growth Regul., 1997, 16, 4, 219-225, https://doi.org/10.1007/PL00007000
. [all data]
Spray, Kobayashi, et al., 1996
Spray, C.R.; Kobayashi, M.; Suzuki, Y.; Phinney, B.O.; Gaskin, P.; MacMillan, J.,
The dwarf-1 (dl) mutant of Zea mays blocks three steps in the gibberellin-biosynthetic pathway,
Proc. Nat. Acad. Sci. U.S.A., 1996, 93, 19, 10515-10518, https://doi.org/10.1073/pnas.93.19.10515
. [all data]
Ridoutt, Pharis, et al., 1995
Ridoutt, B.G.; Pharis, R.P.; Sands, R.,
Identification and quantification of cambial region hormones of Eucalyptus globulus,
Plant Cell Physiol., 1995, 36, 6, 1143-1147. [all data]
Santes, Hedden, et al., 1995
Santes, C.M.; Hedden, P.; Gaskin, P.; Garcia-Martinez, J.L.,
Gibberellins and related compounds in young fruits of pea and their relationship to fruit-set,
Phytochemistry, 1995, 40, 5, 1347-1355, https://doi.org/10.1016/0031-9422(95)00489-T
. [all data]
Talo, Spray, et al., 1995
Talo, A.; Spray, C.R.; Somers, D.A.; Donovan, C.M.; Gaskin, P.; Macmillian, J.; Phinney, B.O.,
Endogenous gibberellins from callus cultures of maize,
Phytochemistry, 1995, 40, 1, 11-15, https://doi.org/10.1016/0031-9422(95)00000-W
. [all data]
Blake and Browning, 1994
Blake, P.S.; Browning, G.,
Gibberellins in developing fruits of Prunus avium,
Phytochemistry, 1994, 35, 6, 1383-1386, https://doi.org/10.1016/S0031-9422(00)86860-0
. [all data]
Hasan, Ridoutt, et al., 1994
Hasan, O.; Ridoutt, B.G.; Ross, J.J.; Davies, N.W.; Reid, J.B.,
Identification and quantification of endogenous gibberellins in apical buds and the cambial region of Eucalyptus,
Physiol. Plant., 1994, 90, 3, 475-480, https://doi.org/10.1111/j.1399-3054.1994.tb08804.x
. [all data]
Kobayashi, Gaskin, et al., 1994
Kobayashi, M.; Gaskin, P.; Spray, C.R.; Phinney, B.O.; MacMillan, J.,
The metabolism of gibberellin A20 to gibberellin A1 by tall and dwarf mutants of Oryza sativa and Arabidopsis thaliana,
Plant Physiol., 1994, 106, 1367-1372. [all data]
Pearce, Koshioka, et al., 1994
Pearce, D.W.; Koshioka, M.; Pharis, R.P.,
Chromatography of gibberellins,
J. Chromatogr. A, 1994, 658, 1, 91-122, https://doi.org/10.1016/0021-9673(94)85210-3
. [all data]
Taylor, Blake, et al., 1994
Taylor, D.R.; Blake, P.S.; Browning, G.,
Identification of gibberellins in leaf tissues of strawberry (Fragaria × ananassa Duch.) grown under different photoperiods,
Plant Growth Regul., 1994, 15, 3, 235-240, https://doi.org/10.1007/BF00029896
. [all data]
Waycott, Smith, et al., 1991
Waycott, W.; Smith, V.A.; Gaskin, P.; MacMillan, J.; Taiz, L.,
The endogenous gibberellins of dwarf mutants of lettuce,
Plant Physiol., 1991, 95, 4, 1169-1173, https://doi.org/10.1104/pp.95.4.1169
. [all data]
Poling and Maier, 1988
Poling, S.M.; Maier, V.P.,
Identification of endogenous gibberellins in navel orange shoots,
Plant Physiol., 1988, 88, 3, 639-642, https://doi.org/10.1104/pp.88.3.639
. [all data]
Heupel R.C., Phinney B.O., et al., 1985
Heupel R.C.; Phinney B.O.; Spray C.R.; Gaskin P.; MacMillan J.; Hedden P.; Graebe J.E.,
Native gibberellins and the metabolism of [14C] gibberellin A53 and of [17-C-13,17-3H)] gibberellin A-20 in tassels of Zea-mays,
Phytochemistry, 1985, 24, 1, 47-53, https://doi.org/10.1016/S0031-9422(00)80805-5
. [all data]
Notes
Go To: Top, Van Den Dool and Kratz RI, non-polar column, custom temperature program, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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