GA29, MeTMSi
- Formula: C26H42O6Si2
- Molecular weight: 506.7791
- IUPAC Standard InChIKey: AINOJINHOWCGRJ-NKPCIVKHSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: GA29 methyl ester TMS ether; GA29, Me-TMS; Gibberelline GA29, methyl ester TMS ether
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- Other data available:
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Normal alkane RI, non-polar column, custom temperature program
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-1 | BPX-5 | BPX-5 | BPX-5 | OV-1 |
Column length (m) | 15. | 25. | 25. | 25. | |
Carrier gas | He | He | He | ||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.22 | 0.22 | 0.22 | |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | |
Program | 60 0C (0.1 min) 20 0C -> 200 0C 5 0C/min -> 300 0C | 60C (1min) => 20C/min => 220C => 4C/min => 300C | 60C (1min) => 20C/min => 220C => 4C/min => 300C | 60C (1min) => 20C/min => 220C => 4C/min => 300C | not specified |
I | 2663. | 2690. | 2692. | 2693. | 2688. |
Reference | Chung, Kuo, et al., 2003 | Stokes, Mander, et al., 2003 | Stokes, Mander, et al., 2003 | Stokes, Mander, et al., 2003 | Sakamoto, Kobayashi, et al., 2001 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-1 | HP-1 | Methyl Silicone | Methyl Silicone | HP-1 |
Column length (m) | 25. | 25. | |||
Carrier gas | Helium | Helium | |||
Substrate | |||||
Column diameter (mm) | 0.20 | 0.20 | |||
Phase thickness (μm) | 0.33 | 0.33 | |||
Program | 60 0C (1 min) 20 0C/min -> 240 0C 4 0C/min -> 300 0C | 60 0C (1 min) 20 0C/min -> 240 0C 4 0C/min -> 300 0C | not specified | not specified | |
I | 2698. | 2701. | 2639. | 2639. | 2682. |
Reference | Fos, Nuez, et al., 2000 | Fos, Nuez, et al., 2000 | Martínez-García, Santes, et al., 2000 | Martínez-García, Santes, et al., 2000 | Ross, MacKenzie-Hose, et al., 1999 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-1 | HP-5 MS | Methyl Silicone | Methyl Silicone | Methyl Silicone |
Column length (m) | 30. | ||||
Carrier gas | Helium | ||||
Substrate | |||||
Column diameter (mm) | 0.25 | ||||
Phase thickness (μm) | 0.25 | ||||
Program | 60 0C 30 K/min -> 230 0C 3 K/min -> 265 0C 30 K/min -> 290 0C | 50 0C (2 min) 10 0C/min -> 150 0C 3 0C/min -> 300 0C | not specified | not specified | not specified |
I | 2684. | 2714. | 2693. | 2693. | 2696. |
Reference | Ross, MacKenzie-Hose, et al., 1999 | van Huizen, Ozga, et al., 1995 | Garcia-Martinez, Santes, et al., 1991 | Garcia-Martinez, Santes, et al., 1991 | Garcia-Martinez, Santes, et al., 1991 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary |
---|---|
Active phase | HP-1 |
Column length (m) | 12. |
Carrier gas | He |
Substrate | |
Column diameter (mm) | 0.2 |
Phase thickness (μm) | 0.33 |
Program | 60C(1min) => 15C/min => 200C => 5C/min => 270C |
I | 2683. |
Reference | Matheussen, Morgan, et al., 1991 |
Comment | MSDC-RI |
References
Go To: Top, Normal alkane RI, non-polar column, custom temperature program, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chung, Kuo, et al., 2003
Chung, J.-D.; Kuo, S.-R.; Chien, C.-T.,
Identification and quantification of gibberellin transformation and dosage changes in good and poor flowering clones of Calocedrus formosana grafts,
Taiwan J. For. Sci., 2003, 18, 4, 387-400. [all data]
Stokes, Mander, et al., 2003
Stokes, T.S.; Mander, L.N.; Croker, S.J.; Twitchin, B.; Hanke, D.E.,
3β,13-Dihydroxylated C20 gibberellins from inflorescences of Rumex acetosa L.,
Phytochemistry, 2003, 62, 2, 165-174, https://doi.org/10.1016/S0031-9422(02)00442-9
. [all data]
Sakamoto, Kobayashi, et al., 2001
Sakamoto, T.; Kobayashi, M.; Itoh, H.; Tahiri, A.; Kayano, T.; Tanaka, H.; Iwahori, S.; Matsuoka, M.,
Expression of a gibberellin 2-oxidase gene around the shoot apex is related to phase transition in rice,
Plant Physiology, 2001, 125, 3, 1508-1516, https://doi.org/10.1104/pp.125.3.1508
. [all data]
Fos, Nuez, et al., 2000
Fos, M.; Nuez, F.; Garcia-Martinez, J.L.,
The gene pat-2, which induces natural partenocarpy, alters the gibberellin content in unpollinated tomato ovaries,
Plant Physiol., 2000, 122, 2, 471-479, https://doi.org/10.1104/pp.122.2.471
. [all data]
Martínez-García, Santes, et al., 2000
Martínez-García, J.F.; Santes, C.M.; García-Martínez, J.L.,
The end-of-day far-red irradiation increases gibberellin A1 content in cowpea (Vigna sinensis) epicotyls by reducing its inactivation,
Physiol. Plant., 2000, 108, 4, 426-434, https://doi.org/10.1034/j.1399-3054.2000.t01-1-100413.x
. [all data]
Ross, MacKenzie-Hose, et al., 1999
Ross, J.J.; MacKenzie-Hose, A.K.; Davies, P.J.; Lester, D.R.; Twitchin, B.; Reid, J.B.,
Further evidence for feedback regulation of gibberellin biosynthesis in pea,
Physiol. Plant., 1999, 105, 3, 532-538, https://doi.org/10.1034/j.1399-3054.1999.105319.x
. [all data]
van Huizen, Ozga, et al., 1995
van Huizen, R.; Ozga, J.A.; Reinecke, D.M.; Twitchin, B.; Mander, L.N.,
Seed and 4-chloroindole-3-acetic acid regulation of gibberellin metabolism in pea pericarp,
Plant Physiol., 1995, 109, 4, 1213-1217, https://doi.org/10.1104/pp.109.4.1213
. [all data]
Garcia-Martinez, Santes, et al., 1991
Garcia-Martinez, J.L.; Santes, C.; Croker, S.J.; Hedden, P.,
Identification, quantitation and distribution of gibberellins in fruits of Pisum sativum L. cv. Alaska during pod development,
Planta, 1991, 184, 1, 53-60, https://doi.org/10.1007/BF00208236
. [all data]
Matheussen, Morgan, et al., 1991
Matheussen, A.-M.; Morgan, P.W.; Frederiksen, R.A.,
Implication of gibberellins in head smut (Sporisorium reilianum) of Sorghum bicolor,
Plant Physiol., 1991, 96, 2, 537-544, https://doi.org/10.1104/pp.96.2.537
. [all data]
Notes
Go To: Top, Normal alkane RI, non-polar column, custom temperature program, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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